Hydrogen bonding-directed supramolecular structural motifs based on 4,4 '-bipyridine dioxide | |
Ma, BQ ; Gao, S ; Sun, HL ; Xu, GX | |
刊名 | crystengcomm
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2001 | |
关键词 | METAL-ORGANIC FRAMEWORK PI-PI-STACKING COORDINATION POLYMERS NETWORKS MOLECULES TPT=2,4,6-TRI(4-PYRIDYL)-1,3,5-TRIAZINE CONSTRUCTION COPPER(II) COMPLEXES CAVITIES |
英文摘要 | Two mononuclear compounds, [Fe(H2O)(5)(dpdo)]SO4.4H(2)O 1 and [Cd(dpdo)(H2O)(3)I-2].0.5dpdo 2 (dpdo=4,4'-bipyridine dioxide) have been obtained from the reactions of (NH4)(2)SO4.FeSO4 or CdI2 with dpdo. The mononuclear units in compound 1 are juxtaposed in head-to-tail mode along the [010] direction and connected through pi-pi stacking and hydrogen bonding to give a ladder-like motif. These ladders are further linked into a 3D network through hydrogen bonding between SO42- anions and water molecules. Compound 2 forms a dimer unit [Cd(dpdo)(H2O)(3)I-2](2) through pi-pi stacking and hydrogen bonding. These dimer subunits and solvated dpdo molecules are alternately arrayed in the [011] plane through pi-pi stacking and hydrogen bonding, leading to a two-dimensional sheet. Intermolecular O . . .I interactions link these sheets, also giving a 3D network.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000170996900001&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Chemistry, Multidisciplinary; Crystallography; SCI(E); 4; ARTICLE; 35; art. no.-35 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/401507] ![]() |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Ma, BQ,Gao, S,Sun, HL,et al. Hydrogen bonding-directed supramolecular structural motifs based on 4,4 '-bipyridine dioxide[J]. crystengcomm,2001. |
APA | Ma, BQ,Gao, S,Sun, HL,&Xu, GX.(2001).Hydrogen bonding-directed supramolecular structural motifs based on 4,4 '-bipyridine dioxide.crystengcomm. |
MLA | Ma, BQ,et al."Hydrogen bonding-directed supramolecular structural motifs based on 4,4 '-bipyridine dioxide".crystengcomm (2001). |
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