Rh(I)-Catalyzed Cross-Coupling of alpha-Diazoesters with Arylsiloxanes

doi:10.1021/acs.orglett.5b00052

CORC > 北京大学 > 化学与分子工程学院

	Rh(I)-Catalyzed Cross-Coupling of alpha-Diazoesters with Arylsiloxanes
	Xia, Ying ; Liu, Zhen ; Feng, Sheng ; Ye, Fei ; Zhang, Yan ; Wang, Jianbo
刊名	organic letters
	2015
关键词	C-C BOND CATALYZED DIRECT ARYLATION N-TOSYLHYDRAZONES ORGANOSILICON REAGENTS ARYLBORONIC ACIDS HIYAMA REACTIONS KINETIC-ANALYSIS DIAZO-COMPOUNDS METAL CARBENE ARYL HALIDES
DOI	10.1021/acs.orglett.5b00052
英文摘要	An Rh(I)-catalyzed cross-coupling of diazoesters with arylsiloxanes has been successfully achieved. This transformation is a new method for the construction of the C(sp(3))C(sp(2)) bond, thus providing an alternative synthesis of a-aryl esters. Rh(I)carbene migratory insertion has been proposed to be involved in this coupling reaction. The reaction represents the first example of utilizing arylsiloxane as the coupling partner in the carbene-involved cross-coupling reactions.; Chemistry, Organic; SCI(E); PubMed; 1; ARTICLE; wangjb@pku.edu.cn; 4; 956-959; 17
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/341487]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Xia, Ying,Liu, Zhen,Feng, Sheng,et al. Rh(I)-Catalyzed Cross-Coupling of alpha-Diazoesters with Arylsiloxanes[J]. organic letters,2015.
APA	Xia, Ying,Liu, Zhen,Feng, Sheng,Ye, Fei,Zhang, Yan,&Wang, Jianbo.(2015).Rh(I)-Catalyzed Cross-Coupling of alpha-Diazoesters with Arylsiloxanes.organic letters.
MLA	Xia, Ying,et al."Rh(I)-Catalyzed Cross-Coupling of alpha-Diazoesters with Arylsiloxanes".organic letters (2015).