Synthesis, crystal structure and physical properties of [Li0.85Fe0.15OH][FeS]

doi:10.1039/c5ra04037j

CORC > 北京大学 > 化学与分子工程学院

	Synthesis, crystal structure and physical properties of [Li0.85Fe0.15OH][FeS]
	Zhang, Xian ; Lai, Xiaofang ; Yi, Na ; He, Jianqiao ; Chen, Haijie ; Zhang, Hui ; Lin, Jianhua ; Huang, Fuqiang
刊名	rsc advances
	2015
DOI	10.1039/c5ra04037j
英文摘要	The layered mixed anion compound with the formula [Li0.85Fe0.15OH][FeS] was synthesized via a facile hydrothermal method. [Li0.85Fe0.15OH][FeS], which is determined by single crystal X-ray diffraction and refined by the SHELXTL program, crystallizes in the tetragonal space group of P4/nmm (a = b = 3.6886(3) ?, c = 8.915(1) ?, V = 121.29(2) ?3, Z = 2). The structure features alternatively packed anti-PbO-like [Li0.85Fe0.15OH] and anti-PbO [FeS] layers. The sample was characterized by Field Emission Scanning Electron Microscopy (FESEM) and High-Resolution Transmission Electron Microscopy (HRTEM). Powder X-ray diffraction results confirm the phase purity of the as-synthesized crystals. Temperature-dependent measurements of magnetic susceptibility reveal the presence of a paramagnetic-to-ferromagnetic phase transition around 50 K, accompanied by the metal-to-semiconductor phase transition in the temperature-dependent resistance of the [Li0.85Fe0.15OH][FeS] single crystal. ? The Royal Society of Chemistry 2015.; SCI(E); EI; 0; ARTICLE; jhlin@pku.edu.cn; huangfq@pku.edu.cn; 48; 38248-38253; 5
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/329119]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Zhang, Xian,Lai, Xiaofang,Yi, Na,et al. Synthesis, crystal structure and physical properties of [Li0.85Fe0.15OH][FeS][J]. rsc advances,2015.
APA	Zhang, Xian.,Lai, Xiaofang.,Yi, Na.,He, Jianqiao.,Chen, Haijie.,...&Huang, Fuqiang.(2015).Synthesis, crystal structure and physical properties of [Li0.85Fe0.15OH][FeS].rsc advances.
MLA	Zhang, Xian,et al."Synthesis, crystal structure and physical properties of [Li0.85Fe0.15OH][FeS]".rsc advances (2015).