REVERSE HEMIMICELLE FORMATION OF 1-DECANOL FROM HEPTANE AT THE SOLUTION   GRAPHITE INTERFACE

doi:10.1016/0166-6622(90)80175-4

CORC > 北京大学 > 化学与分子工程学院

	REVERSE HEMIMICELLE FORMATION OF 1-DECANOL FROM HEPTANE AT THE SOLUTION GRAPHITE INTERFACE
	ZHU, BY ; GU, TR
刊名	colloids and surfaces
	1990
DOI	10.1016/0166-6622(90)80175-4
英文摘要	Based on a two-step adsorption mode (i.e., in the first step the amphiphiles are adsorbed through van der Waals attraction between the amphiphiles and the solid, e.g., carbon black; then, in the second step, the so called reverse hemimicelles form through hydrogen bonding and/or other polar interactions between the adsorbed amphiphiles) and the mass-action law, an isotherm equation is derived for adsorption of amphiphiles on solids from nonpolar solvents. The result has been quantitatively supported by the adsorption data of 1-decanol from heptane at the solution/graphite interface reported by G.H. Findenegg et al. The average aggregation number of the reverse hemimicelles, evaluated from the general adsorption isotherm equation, is in the range of 3-6, in the temperature range of 15-35??C, and decreases with increasing temperature.; Chemistry, Physical; SCI(E); EI; 0; ARTICLE; 2-4; 339-345; 46
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/313576]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	ZHU, BY,GU, TR. REVERSE HEMIMICELLE FORMATION OF 1-DECANOL FROM HEPTANE AT THE SOLUTION GRAPHITE INTERFACE[J]. colloids and surfaces,1990.
APA	ZHU, BY,&GU, TR.(1990).REVERSE HEMIMICELLE FORMATION OF 1-DECANOL FROM HEPTANE AT THE SOLUTION GRAPHITE INTERFACE.colloids and surfaces.
MLA	ZHU, BY,et al."REVERSE HEMIMICELLE FORMATION OF 1-DECANOL FROM HEPTANE AT THE SOLUTION GRAPHITE INTERFACE".colloids and surfaces (1990).