Synthesis of Six-Membered Silacycles

CORC > 北京大学 > 化学与分子工程学院

	Synthesis of Six-Membered Silacycles
	Liu Junhui ; Zhang Shaoguang ; Zhang Wenxiong ; Xi Zhenfeng
刊名	化学进展
	2009
关键词	silacyclohexane silacyclohexene silacyclohexadiene H-B BRIDGES INTRAMOLECULAR HYDROSILYLATION STEREOSELECTIVE-SYNTHESIS UNACTIVATED ALKYNES ORGANIC-SYNTHESIS ENE CYCLIZATIONS SILICON REACTIVITY SILENES ROUTE
英文摘要	Progress in synthetic methodology for six-membered silacycles with one silicon atom in the ring is introduced. Six-membered silacycles are synthesized by the following methods: ring closure by silylation of alpha, omega-dimetallic compounds, [4+2] cycloaddition reaction involving silenes, ring closure by C-Si bond formation, ring closure by C-C bond formation, ring expansion reaction of smaller silacycles, etc. A variety of silacyclohexane, silacyclohexene and silacyclohexadiene derivatives are readily accessible by these transformations.. Further application of six-membered silacycles in organic chemistry and materials science can be envisioned.; Chemistry, Multidisciplinary; SCI(E); 中文核心期刊要目总览(PKU); 中国科技核心期刊(ISTIC); 6; ARTICLE; 7-8; 1475-1486; 21
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/313237]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Liu Junhui,Zhang Shaoguang,Zhang Wenxiong,et al. Synthesis of Six-Membered Silacycles[J]. 化学进展,2009.
APA	Liu Junhui,Zhang Shaoguang,Zhang Wenxiong,&Xi Zhenfeng.(2009).Synthesis of Six-Membered Silacycles.化学进展.
MLA	Liu Junhui,et al."Synthesis of Six-Membered Silacycles".化学进展 (2009).