THE CONFORMATIONAL ANALYSIS AND REACTION MECHANISM FOR HOFMANN   ELIMINATION OF QUATERNARY AMMONIUM HYDROXIDES

doi:10.3866/PKU.WHXB19890405

CORC > 北京大学 > 化学与分子工程学院

	THE CONFORMATIONAL ANALYSIS AND REACTION MECHANISM FOR HOFMANN ELIMINATION OF QUATERNARY AMMONIUM HYDROXIDES
	Xu Xiaojie ; Yao Zhengui ; Ye Xiulin ; Tang Youqi ; Fu Heng ; Qian Minxie
刊名	物理化学学报
	1989
DOI	10.3866/PKU.WHXB19890405
英文摘要	It is known that there are many examples of the thermal elimination of quaternary ammonium hydroxides which do not follow the Hofmann rule. Ye Xiulin et al. proposed the "conformational rule" for the elimination of quaternary ammonium hydroxides, and then, eight quaternary ammonium hydroxides were synthesised and subjected to the elimination. The results show that the conformational rule is superior and acceptable. DPCILO AND CNDO/2 methods were used to calculate the conformational energy of some quaternary ammonium cations with different conformations and the distribution of charge for studying the mechanism of Hofmann elimination reaction. The results show that the conformational rule, based on the conformational energy, can be used to explain the Hofmann elimination reaction well, but the elimination of straight chain alkyl groups other than the ethylic groups should follow cis-E2 elimination mechanism instead of trans-E2 one proposed by Ye Xiulin.; Chemistry, Physical; SCI(E); 中国科学引文数据库(CSCD); 0; 4; 398-402; 5
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/312920]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Xu Xiaojie,Yao Zhengui,Ye Xiulin,et al. THE CONFORMATIONAL ANALYSIS AND REACTION MECHANISM FOR HOFMANN ELIMINATION OF QUATERNARY AMMONIUM HYDROXIDES[J]. 物理化学学报,1989.
APA	Xu Xiaojie,Yao Zhengui,Ye Xiulin,Tang Youqi,Fu Heng,&Qian Minxie.(1989).THE CONFORMATIONAL ANALYSIS AND REACTION MECHANISM FOR HOFMANN ELIMINATION OF QUATERNARY AMMONIUM HYDROXIDES.物理化学学报.
MLA	Xu Xiaojie,et al."THE CONFORMATIONAL ANALYSIS AND REACTION MECHANISM FOR HOFMANN ELIMINATION OF QUATERNARY AMMONIUM HYDROXIDES".物理化学学报 (1989).