Synthesis of Cd(OH)Cl hollow nano-spiremes from a dipolar binary liquid system and their conversion to Cd(OH)(2) hollow nano-spiremes | |
Chen, Guorui ; Gao, Peng ; Wang, Longqiang ; Bao, Di ; Yang, Shaoqiang ; Chen, Yujin ; Wang, Ying ; Li, Guobao ; Sun, Yuzeng | |
刊名 | new journal of chemistry |
2013 | |
关键词 | HYDROGEN STORAGE ABILITY THIN-FILMS ROOM-TEMPERATURE ARRAYS TRANSFORMATION MICROSPHERES CHEMISTRY BATTERIES GROWTH NANOCRYSTALS |
DOI | 10.1039/c2nj41054k |
英文摘要 | A new dipolar binary liquid strategy has been developed for Cd(OH)Cl hollow nano-spireme synthesis, in which different Cd(OH)Cl nanostructures including 1D nanostructures (nanorods, nanobelts, nanowires and nanorod arrays), 2D nanostructures (nanoplates), 3D nanostructures (nanocubes and hollow microspheres) have been easily obtained without using any templates or catalysts. A series of comparison experiments demonstrate that OH- and Cd2+ ion concentrations play significant roles for the nanostructures' formation in this dipolar binary liquid system. Through a simple anion-exchange process at room temperature, the as-prepared Cd(OH)Cl nanostructures (nanowires and hollow nano-spiremes, etc.) have been converted into the corresponding Cd(OH)(2) 1D nanostructures, in which the primary Cd(OH)Cl nano-frameworks can be preserved. Research of the electrochemical properties of Cd(OH)(2) hollow nano-spiremes has demonstrated their high capacity as Ni-Cd battery negative materials due to their interesting ordered hollow nanostructures.; Chemistry, Multidisciplinary; SCI(E); 0; ARTICLE; 3; 815-820; 37 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/290976] |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Chen, Guorui,Gao, Peng,Wang, Longqiang,et al. Synthesis of Cd(OH)Cl hollow nano-spiremes from a dipolar binary liquid system and their conversion to Cd(OH)(2) hollow nano-spiremes[J]. new journal of chemistry,2013. |
APA | Chen, Guorui.,Gao, Peng.,Wang, Longqiang.,Bao, Di.,Yang, Shaoqiang.,...&Sun, Yuzeng.(2013).Synthesis of Cd(OH)Cl hollow nano-spiremes from a dipolar binary liquid system and their conversion to Cd(OH)(2) hollow nano-spiremes.new journal of chemistry. |
MLA | Chen, Guorui,et al."Synthesis of Cd(OH)Cl hollow nano-spiremes from a dipolar binary liquid system and their conversion to Cd(OH)(2) hollow nano-spiremes".new journal of chemistry (2013). |
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