Novel polypyridyl ruthenium(II) complexes for electroluminescence | |
Chuai, YT ; Lee, DN ; Zhen, CG ; Min, JH ; Kim, BH ; Zou, DC | |
刊名 | 合成金属
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2004 | |
关键词 | electroluminescence ruthenium complexes alpha-diimine ligand LIGHT-EMITTING DEVICES ELECTROGENERATED CHEMILUMINESCENCE TRIS(2,2&apos TRISCHELATED RUTHENIUM(II) CONCENTRATION GRADIENTS HIGH-BRIGHTNESS HIGH-EFFICIENCY AMINO-ACIDS TRIS(2,2&apos SYSTEMS -BIPYRIDINE)RUTHENIUM(II) COMPLEXES -BIPYRIDYL)RUTHENIUM(III) |
DOI | 10.1016/j.synthmet.2004.05.015 |
英文摘要 | Several kinds of polypyridyl ruthenium complexes, [Ru(L)(2)(L)](PF6)(2) (L, L' = PBIm-H, bpy, dmbpy, o-phen) were synthesized and applied to single-layered LECs as emitting materials to invent new light-emitting electrochemical cells (LECs) and study the effect of the ligands of Ru (II) complexes on properties of LECs. Emission colors ranging from orange-red to red were obtained by tuning the molecular structure. The current efficiency of newly prepared samples was better than that of known samples [Ru(bPY)(3)](PF6)(2). The device of [Ru(bPY)(2)(dmbpy)](PF6)(2) showed the brightest and most efficient characteristics on the LEC. It operated with a current efficiency of 1.0 cd/A. That efficiency was better than that of the known sample of [Ru(bpy)(2)L](2+) (L = 2,2'-bipyridine-4,4'-dimethanol), which showed an efficiency of 0.6 cd/A. (C) 2004 Elsevier B.V. All rights reserved.; Materials Science, Multidisciplinary; Physics, Condensed Matter; Polymer Science; SCI(E); EI; 0; ARTICLE; 2-3; 259-264; 145 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/254070] ![]() |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Chuai, YT,Lee, DN,Zhen, CG,et al. Novel polypyridyl ruthenium(II) complexes for electroluminescence[J]. 合成金属,2004. |
APA | Chuai, YT,Lee, DN,Zhen, CG,Min, JH,Kim, BH,&Zou, DC.(2004).Novel polypyridyl ruthenium(II) complexes for electroluminescence.合成金属. |
MLA | Chuai, YT,et al."Novel polypyridyl ruthenium(II) complexes for electroluminescence".合成金属 (2004). |
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