Three-dimensional eight- or four-connected metal-organic frameworks   tuned by hydrothermal temperatures

doi:10.1021/cg0700216

CORC > 北京大学 > 化学与分子工程学院

	Three-dimensional eight- or four-connected metal-organic frameworks tuned by hydrothermal temperatures
	Liu, Cai-Ming ; Gao, Song ; Zhang, De-Qing ; Zhu, Dao-Ben
刊名	crystal growth design
	2007
关键词	SECONDARY BUILDING UNITS MAGNETIC-PROPERTIES COORDINATION POLYMER CRYSTAL-STRUCTURE SUPRAMOLECULAR ISOMERISM NETWORK LIGAND TOPOLOGY DESIGN CHEMISTRY
DOI	10.1021/cg0700216
英文摘要	Two novel three-dimensional (3D) metal-organic frameworks (MOFs) with cobalt(II) clusters as nodes and mixed bridging ligands as links, [Co-4(OH)(2)(obbz)(3)(4,4'-bpy)(2)](4,4'-bpy) (obbz(2-) = N,N'-oxamidobis(benzoato), 4,4'-bpy = 4,4'-bipyridine) (1) and [Co-3(H2O)(obbz)(3)(4,4'-bpy)(2)](H2O)(2) (2), were obtained from the same reaction mixture but tuned by different hydrothermal temperatures: the 160 degrees C product 1 is a 3D MOF based on the novel tetranuclear cluster node [Co-4(OH)(2)](6+), displaying a new eight-connected 3(6)4(14)5(4)6(4) topology, whereas the 140 degrees C product 2 is a 2-fold interpenetrating 3D MOF constructed from not only the binuclear cluster node [Co-2(mu(2)-H2O)](4+) but also the mononuclear node Co2+, showing a distorted diamond network.; Chemistry, Multidisciplinary; Crystallography; Materials Science, Multidisciplinary; SCI(E); 0; ARTICLE; 7; 1312-1317; 7
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/250095]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Liu, Cai-Ming,Gao, Song,Zhang, De-Qing,et al. Three-dimensional eight- or four-connected metal-organic frameworks tuned by hydrothermal temperatures[J]. crystal growth design,2007.
APA	Liu, Cai-Ming,Gao, Song,Zhang, De-Qing,&Zhu, Dao-Ben.(2007).Three-dimensional eight- or four-connected metal-organic frameworks tuned by hydrothermal temperatures.crystal growth design.
MLA	Liu, Cai-Ming,et al."Three-dimensional eight- or four-connected metal-organic frameworks tuned by hydrothermal temperatures".crystal growth design (2007).