Synthesis and structure of a 1,6-hexyldiamine heptaborate,   [H3N(CH2)(6)NH3][B7O10(OH)(3)]

doi:10.1016/j.jssc.2007.05.029

CORC > 北京大学 > 化学与分子工程学院

	Synthesis and structure of a 1,6-hexyldiamine heptaborate, [H3N(CH2)(6)NH3][B7O10(OH)(3)]
	Yang, Sihai ; Li, Guobao ; Tian, Shujian ; Lia, Fuhui ; Xiong, Ming ; Lin, Jianhua
刊名	journal of solid state chemistry
	2007
关键词	polyborate heptaborate solvothermal reaction structure space group P2(1)/n supramolecular NONLINEAR-OPTICAL CRYSTAL 1ST EXAMPLES BORATE ANION PENTABORATE POLYANION BORACITE GLASSES CHAINS PHASE AL-27
DOI	10.1016/j.jssc.2007.05.029
英文摘要	A new 1,6-hexyldiamine heptaborate, [H3N(CH2)(6)NH3][B7O10(OH)(3)] (1), has been solvothermally synthesized and characterized by single-crystal X-ray diffraction, FTIR, elemental analysis, and thermogravimetric analysis. Compound I crystallizes in monoclinic system, space group P2(1)/n with a = 8.042(2) angstrom, b = 20.004(4) angstrom, c = 10.103(2) angstrom, and beta = 90.42(3)degrees. The anionic [B7O10(OH)(3)]n(2n-) layers are interlinked via hydrogen bonding to form a 3D supramolecular network containing large channels, in which the templated [H3N(CH2)(6)NH3](2+) cations are located. (C) 2007 Elsevier Inc. All rights reserved.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000249186100006&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Chemistry, Inorganic & Nuclear; Chemistry, Physical; SCI(E); 25; ARTICLE; 8; 2225-2232; 180
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/249971]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Yang, Sihai,Li, Guobao,Tian, Shujian,et al. Synthesis and structure of a 1,6-hexyldiamine heptaborate, [H3N(CH2)(6)NH3][B7O10(OH)(3)][J]. journal of solid state chemistry,2007.
APA	Yang, Sihai,Li, Guobao,Tian, Shujian,Lia, Fuhui,Xiong, Ming,&Lin, Jianhua.(2007).Synthesis and structure of a 1,6-hexyldiamine heptaborate, [H3N(CH2)(6)NH3][B7O10(OH)(3)].journal of solid state chemistry.
MLA	Yang, Sihai,et al."Synthesis and structure of a 1,6-hexyldiamine heptaborate, [H3N(CH2)(6)NH3][B7O10(OH)(3)]".journal of solid state chemistry (2007).