碳/氧化物复合物中碳层对氧化物相变的影响

doi:10.3866/PKU.WHXB20100712

CORC > 北京大学 > 化学与分子工程学院

	碳/氧化物复合物中碳层对氧化物相变的影响; Influence of Carbon on Phase Transformation of Oxides in Carbon/Oxide Composites
	郭颖 ; 王培 ; 隗罡 ; 王羽 ; 朱月香 ; 谢有畅
刊名	物理化学学报
	2010
关键词	碳氧化铝氧化钛相变锐钛矿金红石 Carbon Alumina Titania Phase transformation Anatase Rutile
DOI	10.3866/PKU.WHXB20100712
英文摘要	碳/氧化铝(氧化钛)复合物具有独特的物理化学性质,在吸附和催化过程中有广泛应用.复合物中碳层对氧化物的相变有重要影响.在高温下通氧气焙烧碳/γ-Al2O3复合物可使γ-Al2O3迅速转变为α-Al2O3;而在惰性气氛中,碳层可显著抑制氧化铝的相变与烧结.碳/氧化钛体系中,碳层可明显提高氧化钛在惰性气氛中的热稳定性,在800℃以下碳层能有效阻止锐钛矿相向金红石相的转变;在含氧气氛中控制焙烧条件可将碳层完全除去而基本不影响氧化钛的物相组成及织构.因此,碳层可作为一种特殊的表面修饰剂,既可在高温下抑制氧化物的相变,又可避免在氧化物中引入掺杂元素.; Carbon/alumina (titania) composites have unique physicochemical properties and have been widely used in adsorption and catalysis. Carbon in these composites greatly influences the sintering and phase transformation behavior of the oxides. Calcining carbon/gamma-Al2O3 in oxygen at high temperature results in a quick gamma- to alpha-Al2O3 transformation. In nitrogen, X. ray diffraction (XRD) analysis showed that carbon inhibited the phase transformation significantly. This inhibition effect was found to be carbon content dependent. For the carbon/titania system, pure titania and carbon. protected. titania samples were calcined at different temperatures and analyzed by XRD, transmission electron microscopy (TEM), and Raman spectroscopy. Surface area and pore size analysis was performed by isothermal nitrogen adsorption-desorption. Results show that the carbon layer can improve the thermal stability of the TiO2 nanoparticles and hinder the phase transformation of anatase to rutile at up to 800 degrees C under nitrogen. protected heat treatment. On the other hand, carbon can be removed by controlling calcination in oxygen at 500 degrees C without affecting the phase composition and texture of titania. The carbon removal efficiency was examined by temperature. programmed oxidation (TPO) analysis. Therefore, carbon can be used as a special surface modifier which can inhibit the high temperature phase transformation of oxides without introducing alien elements effectively.; 国家自然科学基金; 国家重点基础研究发展规划项目(973); SCI(E); 中文核心期刊要目总览(PKU); 中国科技核心期刊(ISTIC); 中国科学引文数据库(CSCD); 1; 7; 1887-1892; 26
语种	中文
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/243449]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	郭颖,王培,隗罡,等. 碳/氧化物复合物中碳层对氧化物相变的影响, Influence of Carbon on Phase Transformation of Oxides in Carbon/Oxide Composites[J]. 物理化学学报,2010.
APA	郭颖,王培,隗罡,王羽,朱月香,&谢有畅.(2010).碳/氧化物复合物中碳层对氧化物相变的影响.物理化学学报.
MLA	郭颖,et al."碳/氧化物复合物中碳层对氧化物相变的影响".物理化学学报 (2010).