Challenge and progress: palladium-catalyzed sp(3) C-H activation

doi:10.1039/c0cy00076k

CORC > 北京大学 > 化学与分子工程学院

	Challenge and progress: palladium-catalyzed sp(3) C-H activation
	Li, Hu ; Lia, Bi-Jie ; Shi, Zhang-Jie
刊名	catalysis science technology
	2011
关键词	INTRAMOLECULAR ALKANE ARYLATION AEROBIC OXIDATIVE AMINATION CARBON-HYDROGEN BONDS PYRIDINE N-OXIDES ORGANOMETALLIC CHEMISTRY ALLYLIC ALKYLATION C(SP(3))-H BONDS METHYL-GROUPS ORGANOPALLADIUM(IV) CHEMISTRY HOMOALLYLIC OXIDATION
DOI	10.1039/c0cy00076k
英文摘要	Palladium-catalysis has been broadly applied to sp(2) C-H activation. Recently, palladium-catalyzed sp(3) C-H activation has also been considered as an important strategy to construct synthetically useful C-C/C-X bonds. Allylic sp(3) C-H bonds can be successfully activated by Pd(II) species to produce eta(3)-coordinated palladium species for further transformations, while activation of general sp(3) C-H bonds mainly proceeds through directed pathways with the assistance of proper directing groups or initiated by oxidative addition. Various catalytic mechanisms were extensively investigated through either Pd(II)/Pd(0), Pd(II)/Pd(IV) or Pd(0)/Pd(II) catalytic cycles. The challenges faced in this area have also been addressed in this perspective article.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000294009000004&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Chemistry, Physical; SCI(E); 253; ARTICLE; 2; 191-206; 1
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/241054]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Li, Hu,Lia, Bi-Jie,Shi, Zhang-Jie. Challenge and progress: palladium-catalyzed sp(3) C-H activation[J]. catalysis science technology,2011.
APA	Li, Hu,Lia, Bi-Jie,&Shi, Zhang-Jie.(2011).Challenge and progress: palladium-catalyzed sp(3) C-H activation.catalysis science technology.
MLA	Li, Hu,et al."Challenge and progress: palladium-catalyzed sp(3) C-H activation".catalysis science technology (2011).