Excellent red phosphors of double perovskite Ca2LaMO6:Eu (M=Sb, Nb, Ta)   with distorted coordination environment

doi:10.1016/j.jssc.2011.10.032

CORC > 北京大学 > 化学与分子工程学院

	Excellent red phosphors of double perovskite Ca2LaMO6:Eu (M=Sb, Nb, Ta) with distorted coordination environment
	Yin, Xin ; Wang, Yaoming ; Huang, Fuqiang ; Xia, Yujuan ; Wan, Dongyun ; Yao, Jiyong
刊名	journal of solid state chemistry
	2011
关键词	Double perovskite structure Red luminescence Quantum efficiency TEMPERATURE PHASE-TRANSITIONS LIGHT-EMITTING-DIODES LUMINESCENCE PROPERTIES ENERGY-TRANSFER PHOTOLUMINESCENCE CRYSTAL
DOI	10.1016/j.jssc.2011.10.032
英文摘要	Double perovskite Ca2LaSbO6, successfully synthesized by solid state reaction method, was identified by Rietveld refinements to crystallize in the monoclinic space group P2(1)/n, which is isostructural to Ca2LaMO6 (M=Nb, Ta). Excellent red luminescence of Eu-doped Ca2LaMO6 (M=Sb, Nb, Ta) can be obtained and no luminescence quenching effect was observed when Eu-doping level reached 40%. For Ca2La0.6NbO6:0.4Eu(3+), quantum efficiencies of 20.9% and 27.7% were reached to show high light conversion and bright red emission excited at 465 nm (blue light) and 534 nm (green light), respectively, comparable to the commercial phosphors. Through systemic investigation for the series of double perovskite compounds, the excellent red emission in Ca2LaMO6 is attributed to highly distorted polyhedra of EuO8 (low tolerance factor of the pervoskite), and large bond distances of La-O (low crystal field effect of the activator). (C) 2011 Elsevier Inc. All rights reserved.; Chemistry, Inorganic & Nuclear; Chemistry, Physical; SCI(E); EI; 0; ARTICLE; 12; 3324-3328; 184
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/237407]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Yin, Xin,Wang, Yaoming,Huang, Fuqiang,et al. Excellent red phosphors of double perovskite Ca2LaMO6:Eu (M=Sb, Nb, Ta) with distorted coordination environment[J]. journal of solid state chemistry,2011.
APA	Yin, Xin,Wang, Yaoming,Huang, Fuqiang,Xia, Yujuan,Wan, Dongyun,&Yao, Jiyong.(2011).Excellent red phosphors of double perovskite Ca2LaMO6:Eu (M=Sb, Nb, Ta) with distorted coordination environment.journal of solid state chemistry.
MLA	Yin, Xin,et al."Excellent red phosphors of double perovskite Ca2LaMO6:Eu (M=Sb, Nb, Ta) with distorted coordination environment".journal of solid state chemistry (2011).