Macromolecular structure evolution toward giant molecules of complex   structure: tandem synthesis of asymmetric giant gemini surfactants

doi:10.1039/c4py00107a

CORC > 北京大学 > 化学与分子工程学院

	Macromolecular structure evolution toward giant molecules of complex structure: tandem synthesis of asymmetric giant gemini surfactants
	Su, Hao ; Li, Yiwen ; Yue, Kan ; Wang, Zhao ; Lu, Pengtao ; Feng, Xueyan ; Dong, Xue-Hui ; Zhang, Shuo ; Cheng, Stephen Z. D. ; Zhang, Wen-Bin
刊名	polymer chemistry
	2014
关键词	ENE CLICK CHEMISTRY POLY(TERT-BUTYL ACRYLATE)/POLYSTYRENE BRUSHES POLYHEDRAL OLIGOMERIC SILSESQUIOXANES SHAPE AMPHIPHILES DIMERIC SURFACTANTS CHAIN-LENGTH POLYMER BLOCK NANOPARTICLES ASSEMBLIES
DOI	10.1039/c4py00107a
英文摘要	Precise control of primary chemical structures, especially those of complex structures, is a prerequisite to understand the structure-property relationships of functional macromolecules. In this article, we report the rational design and tandem synthesis of three asymmetric giant gemini surfactants (AGGSs) of complex macromolecular structures based on polyhedral oligomeric silsesquioxane (POSS). In two cascading processes (typically within 5 hours), AGGSs can be synthesized where the length of the two polymer tails and the identity of the two POSS heads can be independently controlled and systematically varied. It represents a convenient, efficient, and modular way to prepare giant molecules with rigorous structural precision in only a few steps. This study expands the scope of synthetically available giant surfactants and facilitates further structural evolution toward even more complex macromolecules.; Polymer Science; SCI(E); EI; 0; ARTICLE; yl48@zips.uakron.edu; scheng@uakron.edu; wenbin@pku.edu.cn; 11; 3697-3706; 5
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/218403]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Su, Hao,Li, Yiwen,Yue, Kan,et al. Macromolecular structure evolution toward giant molecules of complex structure: tandem synthesis of asymmetric giant gemini surfactants[J]. polymer chemistry,2014.
APA	Su, Hao.,Li, Yiwen.,Yue, Kan.,Wang, Zhao.,Lu, Pengtao.,...&Zhang, Wen-Bin.(2014).Macromolecular structure evolution toward giant molecules of complex structure: tandem synthesis of asymmetric giant gemini surfactants.polymer chemistry.
MLA	Su, Hao,et al."Macromolecular structure evolution toward giant molecules of complex structure: tandem synthesis of asymmetric giant gemini surfactants".polymer chemistry (2014).