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Construction of Mesoporous Frameworks with Vanadoborate Clusters
Chen, Hong ; Yu, Zheng-Bao ; Bacsik, Zoltan ; Zhao, Huishuang ; Yao, Qingxia ; Sun, Junliang
刊名angewandte chemie international edition
2014
关键词3D frameworks cluster compounds CO2 adsorption mesoporous materials vanadoborates POROUS MATERIALS EXTENDED SOLIDS BUILDING UNITS GIANT PORES DESIGN CHEMISTRY TEMPERATURE COMPLEXES ZEOLITE OXIDE
DOI10.1002/anie.201311122
英文摘要A new porous vanadoborate was synthesized by employing the scale chemistry theory with the vanadoborate cluster V10B28. The twofold interpenetrated lvt network was assembled with zinc-containing elliptical vanadoborate clusters and Zn polyhedra. The single lvt framework contains a three-dimensional 38x38x20 ring channel system with the pore size (24.7x12.7 angstrom) reaching the mesoscale, thus indicating the possibility of constructing 3D ordered mesopores with vanadoborate clusters. The porosity of the SUT-7 structure was confirmed by CO2 adsorption of the as-synthesized materials.; Chemistry, Multidisciplinary; SCI(E); EI; 5; ARTICLE; junliang.sun@mmk.su.se; 14; 3608-3611; 53
语种英语
内容类型期刊论文
源URL[http://ir.pku.edu.cn/handle/20.500.11897/214181]  
专题化学与分子工程学院
推荐引用方式
GB/T 7714
Chen, Hong,Yu, Zheng-Bao,Bacsik, Zoltan,et al. Construction of Mesoporous Frameworks with Vanadoborate Clusters[J]. angewandte chemie international edition,2014.
APA Chen, Hong,Yu, Zheng-Bao,Bacsik, Zoltan,Zhao, Huishuang,Yao, Qingxia,&Sun, Junliang.(2014).Construction of Mesoporous Frameworks with Vanadoborate Clusters.angewandte chemie international edition.
MLA Chen, Hong,et al."Construction of Mesoporous Frameworks with Vanadoborate Clusters".angewandte chemie international edition (2014).
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