Construction of Mesoporous Frameworks with Vanadoborate Clusters | |
Chen, Hong ; Yu, Zheng-Bao ; Bacsik, Zoltan ; Zhao, Huishuang ; Yao, Qingxia ; Sun, Junliang | |
刊名 | angewandte chemie international edition |
2014 | |
关键词 | 3D frameworks cluster compounds CO2 adsorption mesoporous materials vanadoborates POROUS MATERIALS EXTENDED SOLIDS BUILDING UNITS GIANT PORES DESIGN CHEMISTRY TEMPERATURE COMPLEXES ZEOLITE OXIDE |
DOI | 10.1002/anie.201311122 |
英文摘要 | A new porous vanadoborate was synthesized by employing the scale chemistry theory with the vanadoborate cluster V10B28. The twofold interpenetrated lvt network was assembled with zinc-containing elliptical vanadoborate clusters and Zn polyhedra. The single lvt framework contains a three-dimensional 38x38x20 ring channel system with the pore size (24.7x12.7 angstrom) reaching the mesoscale, thus indicating the possibility of constructing 3D ordered mesopores with vanadoborate clusters. The porosity of the SUT-7 structure was confirmed by CO2 adsorption of the as-synthesized materials.; Chemistry, Multidisciplinary; SCI(E); EI; 5; ARTICLE; junliang.sun@mmk.su.se; 14; 3608-3611; 53 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/214181] |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Chen, Hong,Yu, Zheng-Bao,Bacsik, Zoltan,et al. Construction of Mesoporous Frameworks with Vanadoborate Clusters[J]. angewandte chemie international edition,2014. |
APA | Chen, Hong,Yu, Zheng-Bao,Bacsik, Zoltan,Zhao, Huishuang,Yao, Qingxia,&Sun, Junliang.(2014).Construction of Mesoporous Frameworks with Vanadoborate Clusters.angewandte chemie international edition. |
MLA | Chen, Hong,et al."Construction of Mesoporous Frameworks with Vanadoborate Clusters".angewandte chemie international edition (2014). |
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