有机-无机杂化材料[Ag(bpp)]_2(tdc)·8H_2O的合成,结构和光学性能(bpp=1,3-bis(4-pyridyl)propane,tdc=thiophene-2,5-dicarboxylate)(英文)

doi:10.3321/j.issn:1001-4861.2006.04.003

CORC > 北京大学 > 化学与分子工程学院

	有机-无机杂化材料[Ag(bpp)]_2(tdc)·8H_2O的合成,结构和光学性能(bpp=1,3-bis(4-pyridyl)propane,tdc=thiophene-2,5-dicarboxylate)(英文); Synthesis, crystal structure and optical properties of a novel organic-inorganic hybrid material [Ag(bpp)](2)(tdc)center dot 8H(2)O
	于景华 ; 丁长江 ; 韩克飞 ; 章士伟 ; 郭洪猷
刊名	无机化学学报
	2006
关键词	配位聚合物 3-二吡啶基丙烷合成晶体结构光学性能 1 coordination polymer 1,3-bis(4-pyridyl)propane syntliesis crystal structure optical absorption property
DOI	10.3321/j.issn:1001-4861.2006.04.003
英文摘要	在室温下,AgNO3、1,3-二(4-吡啶基)丙烷和2,5-噻吩二甲酸在丙酮水溶液中反应,经数周后得到完整无色晶体[Ag(bpp)]2(tdc)·8H2O。该晶体由荷正电的类似正弦曲线形状的配位聚合物链,[Ag(bpp)]∞,和有机负离子tdc2-构成,其间分布着起重要作用的结晶水分子。相邻的阳离子链通过静电作用与tdc2-阴离子堆积构成晶体的三维骨架,结晶水分子分布其间并形成氢键,对晶体堆积起定位作用。[Ag(bpp)]2(tdc)·8H2O的晶体学数据:单斜晶系,空间群C2/c,a=3.5447nm,b=0.92003nm,c=2.4119nm,β=106.56°,V=7.546nm3和Z...; The reaction of AgNO3, 1,3-bis(4-pyridyl)propane, thiophene-2,5-dicarboxylate in acetone aqueous solution produces block colourless crystals [Ag(bpp)](2)(tdc) (.) 8H(2)O at room temperature. [Ag(bpp)](2)(tdc) (.) 8H(2)O consists of parallel sinusoid-like cationic chains, [Ag(bpp)]., interspersed with organic tdc(2-) anions which play the role of charge compensation in the crystal structure. The lattice water molecules are situated among these chains and stabilized by rich hydrogen-bonding interactions and lattice water molecules may play a role in the orientation of the tdc(2-) in the crystal packing. The crystal data: monoclinic C2/c, a=3.544 7 nml b=0.92003 nm, c=2.4119 nm, beta=106.56 degrees, V=7.546 nm(3), Z=8. The residual factors based on 6 563 reflections (R-int=0.056 7) are R-1=0.046 3, wR(2)= 0.1142. Optical absorption properties and band gaps of title compound were determined with UVNis/NIR diffuse reflectance spectra. CCDC: 286751.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000236844600003&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; SCI(E); 中文核心期刊要目总览(PKU); 中国科技核心期刊(ISTIC); 中国科学引文数据库(CSCD); 14; 04; 607-611; 22
语种	中文
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/211091]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	于景华,丁长江,韩克飞,等. 有机-无机杂化材料[Ag(bpp)]_2(tdc)·8H_2O的合成,结构和光学性能(bpp=1,3-bis(4-pyridyl)propane,tdc=thiophene-2,5-dicarboxylate)(英文), Synthesis, crystal structure and optical properties of a novel organic-inorganic hybrid material [Ag(bpp)](2)(tdc)center dot 8H(2)O[J]. 无机化学学报,2006.
APA	于景华,丁长江,韩克飞,章士伟,&郭洪猷.(2006).有机-无机杂化材料[Ag(bpp)]_2(tdc)·8H_2O的合成,结构和光学性能(bpp=1,3-bis(4-pyridyl)propane,tdc=thiophene-2,5-dicarboxylate)(英文).无机化学学报.
MLA	于景华,et al."有机-无机杂化材料[Ag(bpp)]_2(tdc)·8H_2O的合成,结构和光学性能(bpp=1,3-bis(4-pyridyl)propane,tdc=thiophene-2,5-dicarboxylate)(英文)".无机化学学报 (2006).