Facile in situ syntheses of new templates and formations of three zinc   phosphates

doi:10.1016/j.inoche.2014.06.025

CORC > 北京大学 > 化学与分子工程学院

	Facile in situ syntheses of new templates and formations of three zinc phosphates
	Wang, Guo-Ming ; Li, Jin-Hua ; Zhang, Xiao ; Jiao, Ji-Qing ; Bao, Zhen-Zhen ; Zhao, Xiao-Meng ; Jiang, Wen-Wen ; Wang, Ying-Xia ; Lin, Jian-Hua
刊名	inorganic chemistry communications
	2014
关键词	Zinc phosphate Crystal structure N-alkylation In situ Solvothermal synthesis OPEN-FRAMEWORK IONOTHERMAL SYNTHESIS COORDINATION POLYMERS HYDROTHERMAL SYNTHESIS 24-RING CHANNELS CONSTRUCTION TRANSFORMATION METHYLATION FLUORESCENT ADSORPTION
DOI	10.1016/j.inoche.2014.06.025
英文摘要	Three new organically templated zinc phosphates, namely, [dmdabco][Zn-2(HPO4)(3)]center dot(H2O) (1), [tmpip](0.5) [Zn-2(HPO4)(2)(H2PO4)] (2) and [tmpip][Zn-3(HPO4)(4)] (3) (dmdabco = N,N'-dimethyl-1,4-diazabicyclo [2,2,2]octane, tmpip = N,N,N',N'-tetramethyl-piperazinium), were successfully synthesized under solvothermal reactions and structurally characterized by single-crystal X-ray diffraction. The dmdabco(2+) and tmpip(2+) templating agents were derived respectively from simple in situ N-alkylation transformations between the methanol solvent and organic cyclic aliphatic diamines, 1,4-diazabicyclo[2,2,2]octane (dabco) in 1 and 1-methylpiperazine in 2 and 3. Such direct methylation feature is unique, and quite different from conventional Eschweiler-Clarke methylation in which an excess of formic acid and formaldehyde was required. Compound 1 exhibits a 4-connected 2D (4,4) net with pentameric [Zn2(HPO4)3] clusters as secondary building units (SBUs); 2 possesses a complex double layered structure with 12-ring windows. Compound 3 has a (3, 4)-connected 3D pcu architecture with heptameric [Zn-3(HPO4)(4)] clusters as SBUs, forming intersecting 8- and 12-ring channels. (C) 2014 Elsevier B.V. All rights reserved.; Chemistry, Inorganic & Nuclear; SCI(E); 0; ARTICLE; gmwang_pub@163.com; 295-300; 46
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/210326]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Wang, Guo-Ming,Li, Jin-Hua,Zhang, Xiao,et al. Facile in situ syntheses of new templates and formations of three zinc phosphates[J]. inorganic chemistry communications,2014.
APA	Wang, Guo-Ming.,Li, Jin-Hua.,Zhang, Xiao.,Jiao, Ji-Qing.,Bao, Zhen-Zhen.,...&Lin, Jian-Hua.(2014).Facile in situ syntheses of new templates and formations of three zinc phosphates.inorganic chemistry communications.
MLA	Wang, Guo-Ming,et al."Facile in situ syntheses of new templates and formations of three zinc phosphates".inorganic chemistry communications (2014).