Synthesis and characterization of a novel ring-like decamolybdate

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	Synthesis and characterization of a novel ring-like decamolybdate
	Liu, G ; Zhang, SW ; Tang, YQ
刊名	journal of the chemical society dalton transactions
	2002
关键词	CRYSTAL-STRUCTURE MOLYBDENUM-OXIDE METAL-OXIDE COMPLEXES CLUSTER COORDINATION WHEEL HETEROPOLYANION OCTAMOLYBDATE CHEMISTRY
DOI	10.1039/b108997h
英文摘要	The reduction of heptamolybdate in acetic aqueous solution resulted in two polymorphic crystals with composition (NH4)(2)[Y(H2O)(5)](2).[(Mo6Mo4O30)-Mo-VI-O-V(CH3COO)(4)].16H(2)O. This polyanion exhibited a novel ring-like decamolybdate structure. Two Y atoms were captured by the polyanion and covered the central hole of the ring. Mo-V-Mo-V bonds were also found in this mixed-valence compound.; Chemistry, Inorganic & Nuclear; SCI(E); EI; 7; ARTICLE; 9; 2036-2039
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/210071]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Liu, G,Zhang, SW,Tang, YQ. Synthesis and characterization of a novel ring-like decamolybdate[J]. journal of the chemical society dalton transactions,2002.
APA	Liu, G,Zhang, SW,&Tang, YQ.(2002).Synthesis and characterization of a novel ring-like decamolybdate.journal of the chemical society dalton transactions.
MLA	Liu, G,et al."Synthesis and characterization of a novel ring-like decamolybdate".journal of the chemical society dalton transactions (2002).