Structures and magnetism of bimetallic octacyanometallates:   honeycomb-like [Mo(CN)(8)Ni-2(pn)(4)](n)center dot 4nH(2)O and binuclear   [Mo(CN)(8)Ni(en)(2)(H2O)][Ni(en)(3)]center dot 2H(2)O   (pn=1,3-diaminopropane, en=1,2-diaminoethane)

doi:10.1016/S1387-7003(02)00518-X

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	Structures and magnetism of bimetallic octacyanometallates: honeycomb-like [Mo(CN)(8)Ni-2(pn)(4)](n)center dot 4nH(2)O and binuclear [Mo(CN)(8)Ni(en)(2)(H2O)][Ni(en)(3)]center dot 2H(2)O (pn=1,3-diaminopropane, en=1,2-diaminoethane)
	Chang, F ; Sun, HL ; Kou, HZ ; Gao, S
刊名	inorganic chemistry communications
	2002
关键词	octacyanometallate honeycomb-like crystal structure magnetism CRYSTAL-STRUCTURE ANISOTROPY CLUSTER NETWORK VALENCE STATE MO
DOI	10.1016/S1387-7003(02)00518-X
英文摘要	Bimetallic octacyanometallates [Mo(CN)(8)Ni-2(pn)(4)](n) . 4nH(2)O (1) and [Mo(CN)(8)Ni(en)(2)(H2O)][Ni(en)(3)] . 2H(2)O (2) based on [Mo(CN)(8)](4-) were synthesized in aqueous solution, and their crystal and molecular structures have been determined. The complex [Mo(CN)(8)Ni-2(pn)(4)](n) . 4nH(2)O (1) consists of novel two-dimensional honeycomb-like layers. The complex [Mo(CN)(8)Ni(en)(2)(H2O)] [Ni(en)(3)] . 2H(2)O (2) contains a binuclear anion [Mo(CN)(8)Ni(en)(2)(H2O)](2-), [Ni(en)(3)](2+) cation and two lattice water molecules. Magnetic studies suggest a possible weak antiferromagnetic interaction between Ni2+ ions in 1. (C) 2002 Elsevier Science B.V. All rights reserved.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000177863300008&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Chemistry, Inorganic & Nuclear; SCI(E); 21; ARTICLE; 9; 660-663; 5
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/208580]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Chang, F,Sun, HL,Kou, HZ,et al. Structures and magnetism of bimetallic octacyanometallates: honeycomb-like [Mo(CN)(8)Ni-2(pn)(4)](n)center dot 4nH(2)O and binuclear [Mo(CN)(8)Ni(en)(2)(H2O)][Ni(en)(3)]center dot 2H(2)O (pn=1,3-diaminopropane, en=1,2-diaminoethane)[J]. inorganic chemistry communications,2002.
APA	Chang, F,Sun, HL,Kou, HZ,&Gao, S.(2002).Structures and magnetism of bimetallic octacyanometallates: honeycomb-like [Mo(CN)(8)Ni-2(pn)(4)](n)center dot 4nH(2)O and binuclear [Mo(CN)(8)Ni(en)(2)(H2O)][Ni(en)(3)]center dot 2H(2)O (pn=1,3-diaminopropane, en=1,2-diaminoethane).inorganic chemistry communications.
MLA	Chang, F,et al."Structures and magnetism of bimetallic octacyanometallates: honeycomb-like [Mo(CN)(8)Ni-2(pn)(4)](n)center dot 4nH(2)O and binuclear [Mo(CN)(8)Ni(en)(2)(H2O)][Ni(en)(3)]center dot 2H(2)O (pn=1,3-diaminopropane, en=1,2-diaminoethane)".inorganic chemistry communications (2002).