Green and efficient synthesis of adipic acid from cyclohexene over   recyclable H3PW4O24/PEHA/ZrSBA-15 with platelet morphology

doi:10.1016/j.micromeso.2014.11.010

CORC > 北京大学 > 化学与分子工程学院

	Green and efficient synthesis of adipic acid from cyclohexene over recyclable H3PW4O24/PEHA/ZrSBA-15 with platelet morphology
	Meng, Lingyan ; Zhai, Shangru ; Sun, Zuchen ; Zhang, Feng ; Xiao, Zuoyi ; An, Qingda
刊名	microporous and mesoporous materials
	2015
关键词	Adipic acid ZrSBA-15 Green synthesis Polyoxometalate Reusability SELECTIVE OXIDATION HYDROGEN-PEROXIDE CATALYTIC-ACTIVITY HETEROPOLY ACID BENZYL ALCOHOL SILICA SBA-15 BENZALDEHYDE METAL SCALE
DOI	10.1016/j.micromeso.2014.11.010
英文摘要	Designing a green synthesis system of adipic acid is important to achieve sustainable development of adipic acid-derived industries. A green and efficient synthesis of adipic acid by using one-step oxidative cleavage of cyclohexene over recyclable H3PW4O24/PEHA/ZrSBA-15 is presented in this paper. The synergic effect of Zr-ions modified the acidic framework and auxiliary PEHA molecules toward high dispersion and stabilization of active clusters. These clusters endowed the resulting nanocomposites with unexceptional reusability under employed reaction conditions. Standard characterization techniques, namely, N-2 sorption, XRD, FT-IR, TEM, XPS, H-1-NMR, and ICP-AES, were performed to establish the coordinated internal ordered framework of the nanocomposite with platelet morphology. The superiority of layer-by-layer deposition strategy has been proved accordingly. Detailed reaction parameters were screened for the optimization of a catalytic system. Compared with the properties of the catalyst H3PW4O24/PEHA/ZrSBA-15, which is prepared through identical pathways, the properties of the reactive PW4 clusters with strengthened stabilization are favorable. Therefore, excellent catalytic performance of adipic acid yield (similar to 90.9%) was observed along with efficient recyclability during five reaction cycles. (C) 2014 Elsevier Inc. All rights reserved.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000347867800016&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Chemistry, Applied; Chemistry, Physical; Nanoscience & Nanotechnology; Materials Science, Multidisciplinary; SCI(E); EI; 1; ARTICLE; zhaisr@dlpu.edu.cn; anqingda@dlpu.edu.cn; C; 123-130; 204
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/206352]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Meng, Lingyan,Zhai, Shangru,Sun, Zuchen,et al. Green and efficient synthesis of adipic acid from cyclohexene over recyclable H3PW4O24/PEHA/ZrSBA-15 with platelet morphology[J]. microporous and mesoporous materials,2015.
APA	Meng, Lingyan,Zhai, Shangru,Sun, Zuchen,Zhang, Feng,Xiao, Zuoyi,&An, Qingda.(2015).Green and efficient synthesis of adipic acid from cyclohexene over recyclable H3PW4O24/PEHA/ZrSBA-15 with platelet morphology.microporous and mesoporous materials.
MLA	Meng, Lingyan,et al."Green and efficient synthesis of adipic acid from cyclohexene over recyclable H3PW4O24/PEHA/ZrSBA-15 with platelet morphology".microporous and mesoporous materials (2015).