Fullerenes as a tert-butylperoxy radical trap, metal catalyzed reaction   of tert-butyl hydroperoxide with fullerenes, and formation of the first   fullerene mixed peroxides C-60(O)((OOBu)-Bu-t)(4) and   C-70((OOBu)-Bu-t)(10)

doi:10.1021/ja027714p

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	Fullerenes as a tert-butylperoxy radical trap, metal catalyzed reaction of tert-butyl hydroperoxide with fullerenes, and formation of the first fullerene mixed peroxides C-60(O)((OOBu)-Bu-t)(4) and C-70((OOBu)-Bu-t)(10)
	Gan, LB ; Huang, SH ; Zhang, XA ; Zhang, AX ; Cheng, BC ; Cheng, H ; Li, XL ; Shang, G
刊名	journal of the american chemical society
	2002
关键词	CHEMISTRY C-60 C70CL10 EPOXIDE TBHP
DOI	10.1021/ja027714p
英文摘要	tert-Butylperoxy radicals generated by TBHP and Ru(PPh3)3Cl2 or other catalysts adds to C60 and C70 to form stable multiadducts, C60(O)(OOtBu)4 and C70(OOtBu)10. The four tert-butylperoxy groups in the C60 mixed peroxide are located around a pentagon, and the epoxy O occupies the remaining 6,6-bond connected to the same pentagon. The C70 decaadduct shows an unprecedented C2 symmetry with the 10 tert-butylperoxy groups added around the central part of C70 by consecutive 1,4-addition. The compounds are fully characterized by spectroscopic data.; Chemistry, Multidisciplinary; SCI(E); EI; PubMed; 110; ARTICLE; 45; 13384-13385; 124
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/200395]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Gan, LB,Huang, SH,Zhang, XA,et al. Fullerenes as a tert-butylperoxy radical trap, metal catalyzed reaction of tert-butyl hydroperoxide with fullerenes, and formation of the first fullerene mixed peroxides C-60(O)((OOBu)-Bu-t)(4) and C-70((OOBu)-Bu-t)(10)[J]. journal of the american chemical society,2002.
APA	Gan, LB.,Huang, SH.,Zhang, XA.,Zhang, AX.,Cheng, BC.,...&Shang, G.(2002).Fullerenes as a tert-butylperoxy radical trap, metal catalyzed reaction of tert-butyl hydroperoxide with fullerenes, and formation of the first fullerene mixed peroxides C-60(O)((OOBu)-Bu-t)(4) and C-70((OOBu)-Bu-t)(10).journal of the american chemical society.
MLA	Gan, LB,et al."Fullerenes as a tert-butylperoxy radical trap, metal catalyzed reaction of tert-butyl hydroperoxide with fullerenes, and formation of the first fullerene mixed peroxides C-60(O)((OOBu)-Bu-t)(4) and C-70((OOBu)-Bu-t)(10)".journal of the american chemical society (2002).