Seeding-Growth of Helical Mesoporous Silica Nanofibers Templated by Achiral Cationic Surfactant | |
Zhou, Longping ; Hong, Guosong ; Qi, Limin ; Lu, Yunfeng | |
刊名 | langmuir |
2009 | |
关键词 | MESOSTRUCTURED SILICA WATER TEMPERATURE CONFINEMENT NANORODS RELEASE ENTROPY FIBERS SHAPES |
DOI | 10.1021/la901083u |
英文摘要 | Helical mesoporous silica nanofibers with parallel nanochannels were synthesized in high yield via a novel seeding-growth method by using the achiral cationic surfactant cetyltrimethylammonium bromide (CTAB) as template without auxiliary additives. A general entropy-driven model taking into account the icelike structure water due to the hydrophobic effect was proposed to explain the formation of helical mesoporous silica nanofibers. It was indicated that helical silica mesostructures could result from a thick layer of highly ordered icelike water around thin silicate seed rods with a proper concentration, which was verified by the effect of various anions and organic additives on the formation of helical mesoporous silica.; Chemistry, Multidisciplinary; Chemistry, Physical; Materials Science, Multidisciplinary; SCI(E); PubMed; 30; ARTICLE; 11; 6040-6044; 25 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/197257] |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Zhou, Longping,Hong, Guosong,Qi, Limin,et al. Seeding-Growth of Helical Mesoporous Silica Nanofibers Templated by Achiral Cationic Surfactant[J]. langmuir,2009. |
APA | Zhou, Longping,Hong, Guosong,Qi, Limin,&Lu, Yunfeng.(2009).Seeding-Growth of Helical Mesoporous Silica Nanofibers Templated by Achiral Cationic Surfactant.langmuir. |
MLA | Zhou, Longping,et al."Seeding-Growth of Helical Mesoporous Silica Nanofibers Templated by Achiral Cationic Surfactant".langmuir (2009). |
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