Transfer of Aryl Halide to Alkyl Halide: Reductive Elimination of   Alkylhalide from Alkylpalladium Halides Containing syn-beta-Hydrogen   Atoms

doi:10.1002/anie.201408341

CORC > 北京大学 > 化学与分子工程学院

	Transfer of Aryl Halide to Alkyl Halide: Reductive Elimination of Alkylhalide from Alkylpalladium Halides Containing syn-beta-Hydrogen Atoms
	Hao, Wei ; Wei, Junnian ; Geng, Weizhi ; Zhang, Wen-Xiong ; Xi, Zhenfeng
刊名	angewandte chemie international edition
	2014
关键词	elimination iodine ligand effects palladium synthetic methods CROSS-COUPLING REACTIONS REVERSIBLE OXIDATIVE ADDITION PALLADIUM-CATALYZED HECK BOND FORMATION ORTHO-ALKYNYLANILINES MECHANISTIC INSIGHT AEROBIC CONDITIONS CARBOIODINATION COMPLEXES IODIDE
DOI	10.1002/anie.201408341
英文摘要	beta-Hydride abstraction is a well-accepted elementary step for catalytic cycles in organometallic chemistry. It is usually anticipated that alkylpalladium halides containing syn-beta-hydrogen atoms will undergo beta-hydride abstraction to afford the Heck-type products. However, this study discloses that the above general knowledge is only conditionally correct. Our experimental results demonstrate that the reductive elimination of alkylhalides from alkylpalladium halides containing syn-beta-hydrogen atoms may surpass the beta-hydride abstraction or even become exclusive in certain cases.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000346485800043&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Chemistry, Multidisciplinary; SCI(E); PubMed; 8; ARTICLE; zfxi@pku.edu.cn; 52; 14533-14537; 53
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/188568]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Hao, Wei,Wei, Junnian,Geng, Weizhi,et al. Transfer of Aryl Halide to Alkyl Halide: Reductive Elimination of Alkylhalide from Alkylpalladium Halides Containing syn-beta-Hydrogen Atoms[J]. angewandte chemie international edition,2014.
APA	Hao, Wei,Wei, Junnian,Geng, Weizhi,Zhang, Wen-Xiong,&Xi, Zhenfeng.(2014).Transfer of Aryl Halide to Alkyl Halide: Reductive Elimination of Alkylhalide from Alkylpalladium Halides Containing syn-beta-Hydrogen Atoms.angewandte chemie international edition.
MLA	Hao, Wei,et al."Transfer of Aryl Halide to Alkyl Halide: Reductive Elimination of Alkylhalide from Alkylpalladium Halides Containing syn-beta-Hydrogen Atoms".angewandte chemie international edition (2014).