Rh-I-Catalyzed Benzo/[7+1] Cycloaddition of   Cyclopropyl-Benzocyclobutenes and CO by Merging Thermal and   Metal-Catalyzed C-C Bond Cleavages

doi:10.1002/chem.201405712

CORC > 北京大学 > 化学与分子工程学院

	Rh-I-Catalyzed Benzo/[7+1] Cycloaddition of Cyclopropyl-Benzocyclobutenes and CO by Merging Thermal and Metal-Catalyzed C-C Bond Cleavages
	Fu, Xu-Fei ; Xiang, Yu ; Yu, Zhi-Xiang
刊名	chemistry a european journal
	2015
关键词	benzo/[7+1] benzocyclobutene carbonylation eight-membered ring rhodium INTRAMOLECULAR 5+2 CYCLOADDITIONS DENSITY-FUNCTIONAL THEORY BETA-CARBON ELIMINATION ELECTROCYCLIC REACTIONS ENE-VINYLCYCLOPROPANES ORGANIC-SYNTHESIS 8-MEMBERED RINGS ACTIVATION INSERTION ALKYNES
DOI	10.1002/chem.201405712
英文摘要	A Rh-catalyzed benzo/[7+1] cycloaddition of cyclopropyl-benzocyclobutenes (CP-BCBs) and CO to benzocyclooctenones has been developed. In this reaction, CPBCB acts as a benzo/7-C synthon and the reaction involves two C-C bond cleavages: a thermal electrocyclic ring-opening of the four-membered ring in CP-BCB and a Rh-catalyzed C-C cleavage of the cyclopropane ring.; Chemistry, Multidisciplinary; SCI(E); PubMed; 2; ARTICLE; yuzx@pku.edu.cn; 11; 4242-4246; 21
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/188399]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Fu, Xu-Fei,Xiang, Yu,Yu, Zhi-Xiang. Rh-I-Catalyzed Benzo/[7+1] Cycloaddition of Cyclopropyl-Benzocyclobutenes and CO by Merging Thermal and Metal-Catalyzed C-C Bond Cleavages[J]. chemistry a european journal,2015.
APA	Fu, Xu-Fei,Xiang, Yu,&Yu, Zhi-Xiang.(2015).Rh-I-Catalyzed Benzo/[7+1] Cycloaddition of Cyclopropyl-Benzocyclobutenes and CO by Merging Thermal and Metal-Catalyzed C-C Bond Cleavages.chemistry a european journal.
MLA	Fu, Xu-Fei,et al."Rh-I-Catalyzed Benzo/[7+1] Cycloaddition of Cyclopropyl-Benzocyclobutenes and CO by Merging Thermal and Metal-Catalyzed C-C Bond Cleavages".chemistry a european journal (2015).