Palladium-Catalyzed Carbonylative Cyclization of Aryl Alkenes/Alkenols:   A New Reaction Mode for the Synthesis of Electron-Rich Chromanes

doi:10.1021/acs.orglett.5b00214

CORC > 北京大学 > 化学与分子工程学院

	Palladium-Catalyzed Carbonylative Cyclization of Aryl Alkenes/Alkenols: A New Reaction Mode for the Synthesis of Electron-Rich Chromanes
	Li, Shuang ; Li, Fuzhuo ; Gong, Jianxian ; Yang, Zhen
刊名	organic letters
	2015
关键词	C-H BONDS OXIDATIVE CARBONYLATION COUPLING REACTIONS DERIVATIVES ACTIVATION ANILINES CARBON HETEROCYCLES NUCLEOPHILES CHROMENES
DOI	10.1021/acs.orglett.5b00214
英文摘要	The Pd(II)-catalyzed intramolecular carbonylative cyclization reaction of aryl alkenes and aryl alkenols is reported for the synthesis of structurally diverse chromanes. PdCl2(CH3CN)(2) was used as the catalyst and CuCl2 as the oxidant under the balloon pressure of CO. The reaction is conducted under mild conditions, and chromane-type esters and lactones can be generated in a highly regio- and stereoselective manner.; Chemistry, Organic; SCI(E); PubMed; 0; ARTICLE; gongjx@pku.edu.cn; zyang@pku.edu.cn; 5; 1240-1243; 17
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/188288]
专题	化学与分子工程学院生命科学学院
推荐引用方式 GB/T 7714	Li, Shuang,Li, Fuzhuo,Gong, Jianxian,et al. Palladium-Catalyzed Carbonylative Cyclization of Aryl Alkenes/Alkenols: A New Reaction Mode for the Synthesis of Electron-Rich Chromanes[J]. organic letters,2015.
APA	Li, Shuang,Li, Fuzhuo,Gong, Jianxian,&Yang, Zhen.(2015).Palladium-Catalyzed Carbonylative Cyclization of Aryl Alkenes/Alkenols: A New Reaction Mode for the Synthesis of Electron-Rich Chromanes.organic letters.
MLA	Li, Shuang,et al."Palladium-Catalyzed Carbonylative Cyclization of Aryl Alkenes/Alkenols: A New Reaction Mode for the Synthesis of Electron-Rich Chromanes".organic letters (2015).