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	The first lutetacyclopentadienes: synthesis, structure, and diversified insertion/c?h activation reactivity
	Xu Ling ; Wang Yu-Chen ; Wei Junnian ; Wang Yang ; Wang Zitao ; Zhang Wen-Xiong ; Xi Zhenfeng
刊名	chemistry weinheim an der bergstrasse germany
	2015
关键词	1,4-dilithio-1,3-butadienes,insertion reactions,metallacyclopentadienes,rare-earth metals
DOI	10.1002/chem.201500387
英文摘要	The first well-defined lutetacyclopentadienes are synthesised from pentamethylcyclopentadienyl lithium (Cp*Li), 1,4-dilithio-1,3-butadienes, and LuCl3 . The lutetacyclopentadiene shows excellent reactivity towards some small molecules, such as pivalaldehyde, Se, carbon dioxide, and isonitrile to efficiently construct 3-, 5-, 7-, 8-, and 9-membered rare-earth metallacycles. Both monoinsertion and double-insertion of two Lu?C?sp?2 bonds are observed. Specially, the reaction between lutetacyclopentadiene and isonitrile afforded [3,5,5]-fused metallacycles. The distinguished reactivity can be attributed to the highly ionic character and the cooperative reactivity of two Lu?C?sp?2 bonds.? 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.; SCI(E); PubMed; 0; ARTICLE; wx_zhang@pku.edu.cn; 18; 6686-9; 21
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/188231]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Xu Ling,Wang Yu-Chen,Wei Junnian,et al. The first lutetacyclopentadienes: synthesis, structure, and diversified insertion/c?h activation reactivity[J]. chemistry weinheim an der bergstrasse germany,2015.
APA	Xu Ling.,Wang Yu-Chen.,Wei Junnian.,Wang Yang.,Wang Zitao.,...&Xi Zhenfeng.(2015).The first lutetacyclopentadienes: synthesis, structure, and diversified insertion/c?h activation reactivity.chemistry weinheim an der bergstrasse germany.
MLA	Xu Ling,et al."The first lutetacyclopentadienes: synthesis, structure, and diversified insertion/c?h activation reactivity".chemistry weinheim an der bergstrasse germany (2015).

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