Amine groups-functionalized alcohol-soluble polyfluorene derivatives:   Synthesis, photophysical properties, and self-assembly behaviors

doi:10.1016/j.polymer.2009.08.028

CORC > 北京大学 > 化学与分子工程学院

	Amine groups-functionalized alcohol-soluble polyfluorene derivatives: Synthesis, photophysical properties, and self-assembly behaviors
	Guo, Zeng-Shan ; Pei, Jian ; Zhou, Zhang-Lin ; Zhao, Lihua ; Gibson, Gary ; Lam, Sity ; Brug, James
刊名	polymer
	2009
关键词	Electroluminescence Self-assembly Hydrogen bonding LIGHT-EMITTING-DIODES LIQUID-CRYSTALLINE POLYFLUORENE FIELD-EFFECT TRANSISTORS THIN-FILM TRANSISTORS CONJUGATED POLYMERS POLARIZED ELECTROLUMINESCENCE MOLECULAR-WEIGHT HIGH-EFFICIENCY HIGH-MOBILITY SOLAR-CELLS
DOI	10.1016/j.polymer.2009.08.028
英文摘要	A polyfluorene derivative with primary amine groups on side chains, poly(9,9-bis(6'-aminohexyl)fluorene) (PF-NH(2)), was prepared through de-protection of its analogue polymer poly(9,9-bis(6'-butoxylcarbonylaminohexyl)fluorene) (PF-BOC) with hydrochloric acid followed by neutralizing the salt form of poly(6,6'-(9H-fluorene-9,9-diyl)dihexan-1-aminium chloride) (PF-NION). PF-NION had good solubility in methanol, DMSO, and DMF. Scanning electron microscopic images of PF-NH(2) in thin films revealed that intramolecular/intermolecular hydrogen bonding and pi-pi stacking interactions probably played an important role in the formation of special surface morphologies, which might be beneficial to the molecular ordering and device fabrication. The electroluminescence property of PF-NION was recorded on a simple polymer light-emitting diode (PLED) device configuration of ITO/PEDOT/Polymer/Al. Pure blue electroluminescence is achieved from double-layer PLEDs based on PF-NION as the active material with the CIE of (0.16, 0.08). (C) 2009 Elsevier Ltd. All rights reserved.; Polymer Science; SCI(E); 0; ARTICLE; 20; 4794-4800; 50
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/151379]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Guo, Zeng-Shan,Pei, Jian,Zhou, Zhang-Lin,et al. Amine groups-functionalized alcohol-soluble polyfluorene derivatives: Synthesis, photophysical properties, and self-assembly behaviors[J]. polymer,2009.
APA	Guo, Zeng-Shan.,Pei, Jian.,Zhou, Zhang-Lin.,Zhao, Lihua.,Gibson, Gary.,...&Brug, James.(2009).Amine groups-functionalized alcohol-soluble polyfluorene derivatives: Synthesis, photophysical properties, and self-assembly behaviors.polymer.
MLA	Guo, Zeng-Shan,et al."Amine groups-functionalized alcohol-soluble polyfluorene derivatives: Synthesis, photophysical properties, and self-assembly behaviors".polymer (2009).