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Sensitized luminescence from lanthanides in d-f bimetallic complexes
Chen, Fang-Fang ; Chen, Zhu-Qi ; Bian, Zu-Qiang ; Huang, Chun-Hui
刊名coordination chemistry reviews
2010
关键词Bimetallic complexes Transition metals Lanthanides Red emission NIR emission NEAR-INFRARED LUMINESCENCE INTRAMOLECULAR ENERGY TRANSFER SCHIFF-BASE COMPLEXES ZN-ND COMPLEXES TERPYRIDYL-FUNCTIONALIZED ALKYNYL ANCILLARY OLIGOPYRIDINE LIGANDS VISIBLE-LIGHT SENSITIZATION TRANSITION-METAL COMPLEXES RARE-EARTH COMPLEXES PHOTOPHYSICAL PROPERTIES
DOI10.1016/j.ccr.2009.12.028
英文摘要This article reviews progress in the research of transition metal-lanthanide (d-f) bimetallic complexes Through efficient energy transfer, sensitized luminescence of lanthanide ions from the visible range (Eu(III)) to the near-infrared region (Nd(III), Yb(III), Er(III) and Pr(III)) is obtained in these bimetallic assembles The d-block in d-f bimetallic complexes mainly contributes to the improvement of lanthanide emission efficiency and the extension of the excitation window for the lanthanide complexes. Examples are catalogued by various transition metals, such as Ru(II), Os(II) (Fe(II)), Pt(II) (Au(I)), Pd(II), Cr(III), Co(III), Zn(II) and Ir(III). The relevant synthetic procedures, crystal structures and photophysical properties of these d-f complexes are briefly described Additionally, the molecular properties responsible for the performance of certain d-f systems, such as energy levels, nuclear distances and coordination environments, will be discussed (C) 2009 Elsevier B.V. All rights reserved.; Chemistry, Inorganic & Nuclear; SCI(E); 92; REVIEW; 9-10,SI; 991-1010; 254
语种英语
内容类型期刊论文
源URL[http://ir.pku.edu.cn/handle/20.500.11897/151197]  
专题化学与分子工程学院
推荐引用方式
GB/T 7714
Chen, Fang-Fang,Chen, Zhu-Qi,Bian, Zu-Qiang,et al. Sensitized luminescence from lanthanides in d-f bimetallic complexes[J]. coordination chemistry reviews,2010.
APA Chen, Fang-Fang,Chen, Zhu-Qi,Bian, Zu-Qiang,&Huang, Chun-Hui.(2010).Sensitized luminescence from lanthanides in d-f bimetallic complexes.coordination chemistry reviews.
MLA Chen, Fang-Fang,et al."Sensitized luminescence from lanthanides in d-f bimetallic complexes".coordination chemistry reviews (2010).
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