Direct catalytic oxidation of benzene to phenol over metal-free   graphene-based catalyst

doi:10.1039/c3ee23623d

CORC > 北京大学 > 化学与分子工程学院

	Direct catalytic oxidation of benzene to phenol over metal-free graphene-based catalyst
	Yang, Jing-He ; Sun, Geng ; Gao, Yongjun ; Zhao, Huabo ; Tang, Pei ; Tan, Juan ; Lu, An-Hui ; Ma, Ding
刊名	energy environmental science
	2013
关键词	HYDROGEN-PEROXIDE DIRECT HYDROXYLATION CARBON DECOMPOSITION OXYGEN OXIDE TS-1 DEHYDROGENATION SELECTIVITY
DOI	10.1039/c3ee23623d
英文摘要	We report an efficient, highly selective, and low temperature graphene-catalyzed reaction process for one-step oxidation of benzene to phenol with hydrogen peroxide as the oxidant. The chemically converted graphene (CCG) from small graphite was used as the catalyst. The conversion of benzene reaches 18%, with phenol being the sole product. The catalyst was reusable and very stable. By XPS, C K-edge X-ray absorption spectra, benzene-TPD, and kinetic measurements, it was concluded that the moderate H2O2 activation rate, good benzene adsorption ability, and balanced kinetic control over the oxidation reaction are responsible for the outstanding catalytic performance of the metal-free catalyst.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000315165700011&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Chemistry, Multidisciplinary; Energy & Fuels; Engineering, Chemical; Environmental Sciences; SCI(E); EI; 54; ARTICLE; 3; 793-798; 6
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/150791]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Yang, Jing-He,Sun, Geng,Gao, Yongjun,et al. Direct catalytic oxidation of benzene to phenol over metal-free graphene-based catalyst[J]. energy environmental science,2013.
APA	Yang, Jing-He.,Sun, Geng.,Gao, Yongjun.,Zhao, Huabo.,Tang, Pei.,...&Ma, Ding.(2013).Direct catalytic oxidation of benzene to phenol over metal-free graphene-based catalyst.energy environmental science.
MLA	Yang, Jing-He,et al."Direct catalytic oxidation of benzene to phenol over metal-free graphene-based catalyst".energy environmental science (2013).