Preparation and Dehydrogenation Properties of Lithium   Hydrazidobis(borane) (LiNH(BH3)NH2BH3)

doi:10.1021/ic500679b

CORC > 北京大学 > 化学与分子工程学院

	Preparation and Dehydrogenation Properties of Lithium Hydrazidobis(borane) (LiNH(BH3)NH2BH3)
	Fu, He ; Yang, Junzhi ; Wang, Xiaojuan ; Xin, Gongbiao ; Zheng, Jie ; Li, Xingguo
刊名	inorganic chemistry
	2014
关键词	CHEMICAL HYDROGEN-STORAGE HIGH-EXTENT DEHYDROGENATION AMMONIA BORANE THERMAL-DECOMPOSITION HYDRAZINE BORANE REDUCING AGENTS AMIDOBORANE POWERFUL RELEASE AMINOBOROHYDRIDES
DOI	10.1021/ic500679b
英文摘要	LiNH(BH3)NH2BH3, the first example of metal-substituted hydrazine bisborane (HBB), is synthesized via the reaction between HBB and n-butyllithium in ether solution. B-11 NW. and Fourier transform infrared spectroscopy indicate a new structure, in which one of the N-H bonds is replaced by a N-Li bond. The X-ray diffraction pattern of the product also indicates the formation of a new crystal structure. This compound releases hydrogen at 126 and 170 degrees C with satisfactory purity and exhibits superior hydrogen storage properties compared with HBB. Differential scanning calorimetry measurement suggests the dehydrogenation reaction of this compound is less exothermic than that of HBB.; Chemistry, Inorganic & Nuclear; SCI(E); PubMed; 2; ARTICLE; xgli@pku.edu.cn; 14; 7334-7339; 53
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/149695]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Fu, He,Yang, Junzhi,Wang, Xiaojuan,et al. Preparation and Dehydrogenation Properties of Lithium Hydrazidobis(borane) (LiNH(BH3)NH2BH3)[J]. inorganic chemistry,2014.
APA	Fu, He,Yang, Junzhi,Wang, Xiaojuan,Xin, Gongbiao,Zheng, Jie,&Li, Xingguo.(2014).Preparation and Dehydrogenation Properties of Lithium Hydrazidobis(borane) (LiNH(BH3)NH2BH3).inorganic chemistry.
MLA	Fu, He,et al."Preparation and Dehydrogenation Properties of Lithium Hydrazidobis(borane) (LiNH(BH3)NH2BH3)".inorganic chemistry (2014).