聚N-对羟苯基丙烯酰胺与重氮树脂的氢键自组装; Self-assembly of diazoresin and P[N-(4-hydroxyphenyl)acrylamide via H-bonding interaction | |
杨朝辉 ; 曹廷炳 ; 陈金玉 ; 曹维孝 | |
2002 | |
关键词 | 聚N-对羟苯基丙烯酰胺 重氮树脂 光活性多层膜 氢键自组装 4-N-hydroxyphenyl acrylamide diazoresin photoactive multilayer films hydrogen bond self-assembly |
英文摘要 | The self assembly between diazoresin(DR) and the homopolymer or copolymers of 4 N hydroxyphenyl acrylamide(NHPA) has been investigated.It was confirmed that the driven force of the assembly is H bonding attraction, in which the DR plays a role of H acceptor, while the NHPA polymers act as a...; The self-assembly between diazoresin(DR) and the homopolymer or copolymers of 4-N-hydroxyphenyl acrylamide(NHPA) has been investigated. It was confirmed that the driven force of the assembly is H-bonding attraction, in which the DR plays a role of H-acceptor, while the NHPA polymers act as a H-donor, Under UV, the multiayer films become very stable towards polar solvents. For example, no any change was observed when the irradiated film was immersed in DMF at 20 degreesC for 12 h, but the unirradiated film was destroyled completely when it was immersed in DMF at the same temperature for 20 min. The dramatically improvement for the stability of the film towards polar solvents should be attributed to the bond conversion of the layers from H-bond to covalent bond under UV irradiation.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000174163300048&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; SCI(E); 中文核心期刊要目总览(PKU); 中国科技核心期刊(ISTIC); 中国科学引文数据库(CSCD); 2; 02; 342-344; 23 |
语种 | 中文 |
出处 | 万方 ; 知网 ; SCI |
出版者 | 高等学校化学学报 |
内容类型 | 其他 |
源URL | [http://hdl.handle.net/20.500.11897/78391] |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | 杨朝辉,曹廷炳,陈金玉,等. 聚N-对羟苯基丙烯酰胺与重氮树脂的氢键自组装, Self-assembly of diazoresin and P[N-(4-hydroxyphenyl)acrylamide via H-bonding interaction. 2002-01-01. |
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