Efficient and Highly Selective Solvent-Free Oxidation of Primary Alcohols to Aldehydes Using Bucky Nanodiamond

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	Efficient and Highly Selective Solvent-Free Oxidation of Primary Alcohols to Aldehydes Using Bucky Nanodiamond
	Lin, Yangming; Wu, Kuang-Hsu (Tim); Yu, Linhui; Heumann, Saskia; Su, Dang Sheng; Su, DS (reprint author), Chinese Acad Sci, Inst Met Res, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China.; Su, DS (reprint author), Fritz Haber Inst Max, Dept Inorgan Chem, Planck Soc, Faradayweg 4-6, D-14195 Berlin, Germany.
刊名	WILEY-V C H VERLAG GMBH
	2017-09-11
卷号	10 期号:17 页码:3497-3505
关键词	Alcohols Carbocatalysis Electrochemistry Oxidation Redox Reactions
ISSN号	1864-5631
英文摘要	Selective oxidation of alcohols to aldehydes is widely applicable to the synthesis of various green chemicals. The poor chemoselectivity for complicated primary aldehydes over state-of-the-art metal-free or metal-based catalysts represents a major obstacle for industrial application. Bucky nanodiamond is a potential green catalyst that exhibits excellent chemoselectivity and cycling stability for the selective oxidation of primary alcohols in diverse structures (22examples, including aromatic, substituted aromatic, unsaturated, heterocyclic, and linear chain alcohols) to their corresponding aldehydes. The results are comparable to reported transition-metal catalysts including conventional Pt/C and Ru/C catalysts for certain substrates under solvent-free conditions. The possible activation process of the oxidant and substrates by the surface oxygen groups and defect species are revealed with model catalysts, exsitu electrochemical measurements, and exsitu attenuated total reflectance. The zigzag edges of sp(2) carbon planes are shown to play a key role in these reactions.; Selective oxidation of alcohols to aldehydes is widely applicable to the synthesis of various green chemicals. The poor chemoselectivity for complicated primary aldehydes over state-of-the-art metal-free or metal-based catalysts represents a major obstacle for industrial application. Bucky nanodiamond is a potential green catalyst that exhibits excellent chemoselectivity and cycling stability for the selective oxidation of primary alcohols in diverse structures (22examples, including aromatic, substituted aromatic, unsaturated, heterocyclic, and linear chain alcohols) to their corresponding aldehydes. The results are comparable to reported transition-metal catalysts including conventional Pt/C and Ru/C catalysts for certain substrates under solvent-free conditions. The possible activation process of the oxidant and substrates by the surface oxygen groups and defect species are revealed with model catalysts, exsitu electrochemical measurements, and exsitu attenuated total reflectance. The zigzag edges of sp(2) carbon planes are shown to play a key role in these reactions.
学科主题	Chemistry, Multidisciplinary ; Green & Sustainable Science & Technology
语种	英语
资助机构	Strategic Priority Research Program of the Chinese Academy of Sciences [XDA09030103]
公开日期	2018-01-10
内容类型	期刊论文
源URL	[http://ir.imr.ac.cn/handle/321006/79100]
专题	金属研究所_中国科学院金属研究所
通讯作者	Su, DS (reprint author), Chinese Acad Sci, Inst Met Res, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China.; Su, DS (reprint author), Fritz Haber Inst Max, Dept Inorgan Chem, Planck Soc, Faradayweg 4-6, D-14195 Berlin, Germany.
推荐引用方式 GB/T 7714	Lin, Yangming,Wu, Kuang-Hsu ,Yu, Linhui,et al. Efficient and Highly Selective Solvent-Free Oxidation of Primary Alcohols to Aldehydes Using Bucky Nanodiamond[J]. WILEY-V C H VERLAG GMBH,2017,10(17):3497-3505.
APA	Lin, Yangming.,Wu, Kuang-Hsu .,Yu, Linhui.,Heumann, Saskia.,Su, Dang Sheng.,...&Su, DS .(2017).Efficient and Highly Selective Solvent-Free Oxidation of Primary Alcohols to Aldehydes Using Bucky Nanodiamond.WILEY-V C H VERLAG GMBH,10(17),3497-3505.
MLA	Lin, Yangming,et al."Efficient and Highly Selective Solvent-Free Oxidation of Primary Alcohols to Aldehydes Using Bucky Nanodiamond".WILEY-V C H VERLAG GMBH 10.17(2017):3497-3505.