Tunable Thermal Expansion from Negative, Zero, to Positive in Cubic Prussian Blue Analogues of GaFe(CN)(6)

doi:10.1021/acs.inorgchem.8b02428

	Tunable Thermal Expansion from Negative, Zero, to Positive in Cubic Prussian Blue Analogues of GaFe(CN)(6)
	Zheng, Lirong, Chen, Jun; Zheng LR(郑黎荣); Xing, Xianran; Gao, Qilong, Shi, Naike, Sanson,; rea, Sun, Yu, Milazzo, Ruggero, Olivi, Luca, Zhu, He, Lapidus, Saul H.
刊名	INORGANIC CHEMISTRY
	2018
卷号	57 期号:22 页码:14027-14030
ISSN号	0020-1669
DOI	10.1021/acs.inorgchem.8b02428
文献子类	Article
英文摘要	The achievement of controlling thermal expansion is important for open-framework structures. The present work proposes a feasible way to adjust the coefficient of thermal expansion continuously from negative to positive via inserting guest Na+ ions or H2O molecules into a GaFe(CN)(6) framework. The guest ions or molecules have an intense dampening effect on the transverse vibrations of CN atoms in the -Ga-N C- Fe- linkage, especially for the N atoms. This study demonstrates that electrochemical or redox intercalation of guest ions will be an effective way to tune thermal expansion in those negative thermal expansion open framework materials induced by low-frequency phonons.
电子版国际标准刊号	1520-510X
WOS关键词	CRYSTAL
WOS研究方向	Chemistry
语种	英语
WOS记录号	WOS:000451244700051
内容类型	期刊论文
源URL	[http://ir.ihep.ac.cn/handle/311005/286863]
专题	高能物理研究所_多学科研究中心
作者单位	中国科学院高能物理研究所
推荐引用方式 GB/T 7714	Zheng, Lirong, Chen, Jun,Zheng LR,Xing, Xianran,et al. Tunable Thermal Expansion from Negative, Zero, to Positive in Cubic Prussian Blue Analogues of GaFe(CN)(6)[J]. INORGANIC CHEMISTRY,2018,57(22):14027-14030.
APA	Zheng, Lirong, Chen, Jun,郑黎荣,Xing, Xianran,Gao, Qilong, Shi, Naike, Sanson,,&rea, Sun, Yu, Milazzo, Ruggero, Olivi, Luca, Zhu, He, Lapidus, Saul H..(2018).Tunable Thermal Expansion from Negative, Zero, to Positive in Cubic Prussian Blue Analogues of GaFe(CN)(6).INORGANIC CHEMISTRY,57(22),14027-14030.
MLA	Zheng, Lirong, Chen, Jun,et al."Tunable Thermal Expansion from Negative, Zero, to Positive in Cubic Prussian Blue Analogues of GaFe(CN)(6)".INORGANIC CHEMISTRY 57.22(2018):14027-14030.