Enhancing the Activity and Thermal Stability of Nickel Complex Precatalysts Using 1-[2,6-Bis(bis(4-fluorophenyl)methyl)-4-methyl phenylimino]-2-aryliminoacenaphthylene Derivatives

doi:10.1021/om500943u

	Enhancing the Activity and Thermal Stability of Nickel Complex Precatalysts Using 1-[2,6-Bis(bis(4-fluorophenyl)methyl)-4-methyl phenylimino]-2-aryliminoacenaphthylene Derivatives
	Du, SZ; Kong, SL; Shi, QS; Mao, J; Guo, CY; Yi, JJ; Liang, TL; Sun, WH
刊名	ORGANOMETALLICS
	2015-02-09
卷号	34 期号:3 页码:582-590
ISSN号	0276-7333
DOI	10.1021/om500943u
英文摘要	The series of acenaphthylene-1-[2,6-bis(bis(4-fluorophenyl)methyl)-4-methylphenylimino]-2-arylimine derivatives and their dichloronickel complexes were synthesized and fully characterized as well as the single-crystal X-ray diffraction of representative nickel complexes, revealing a distorted tetrahedral geometry. Upon activation with either MAO or Et2AlCl, all nickel complexes showed high activities in ethylene polymerization; moreover, their catalytic systems showed better thermal stabilities on being manipulated at 80 degrees C as the industrial operating temperature.
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000349273900008
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/41986]
专题	化学研究所_工程塑料实验室
作者单位	Sun, WH (reprint author), Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing 100190, Peoples R China.
推荐引用方式 GB/T 7714	Du, SZ,Kong, SL,Shi, QS,et al. Enhancing the Activity and Thermal Stability of Nickel Complex Precatalysts Using 1-[2,6-Bis(bis(4-fluorophenyl)methyl)-4-methyl phenylimino]-2-aryliminoacenaphthylene Derivatives[J]. ORGANOMETALLICS,2015,34(3):582-590.
APA	Du, SZ.,Kong, SL.,Shi, QS.,Mao, J.,Guo, CY.,...&Sun, WH.(2015).Enhancing the Activity and Thermal Stability of Nickel Complex Precatalysts Using 1-[2,6-Bis(bis(4-fluorophenyl)methyl)-4-methyl phenylimino]-2-aryliminoacenaphthylene Derivatives.ORGANOMETALLICS,34(3),582-590.
MLA	Du, SZ,et al."Enhancing the Activity and Thermal Stability of Nickel Complex Precatalysts Using 1-[2,6-Bis(bis(4-fluorophenyl)methyl)-4-methyl phenylimino]-2-aryliminoacenaphthylene Derivatives".ORGANOMETALLICS 34.3(2015):582-590.