Synthesis and functionalization of isotactic poly(propylene) containing pendant styrene groups

doi:10.1002/marc.200400284

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	Synthesis and functionalization of isotactic poly(propylene) containing pendant styrene groups
	Zou, JF ; Cao, CG ; Dong, JY ; Hu, YL ; Chung, TC
刊名	MACROMOLECULAR RAPID COMMUNICATIONS
	2004-10-22
卷号	25 期号:20 页码:1797-1804
关键词	Catalysts Copolymerization Graft Copolymers 1 4-divinylbenzene
ISSN号	1022-1336
DOI	10.1002/marc.200400284
英文摘要	Copolymerization of propylene and 1,4-divinyl-benzene was successfully performed by a MgCl2-supported TiCl4 catalyst, yielding isotactic poly(propylene) (i-PP) polymers containing a few pendant styrene groups. With a metalation reaction with butyllithium and a hydrochlorination reaction with dry hydrogen chloride, the pendant styrene groups were quantitatively transformed into benzyllithium and 1-chloroethylbenzene groups, respectively, which allowed the synthesis of i-PP-based graft copolymers by living anionic and atom transfer radical (ATRP) polymerization mechanisms.
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000224948200008
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/82443]
专题	中国科学院化学研究所
通讯作者	Dong, JY
作者单位	1.Chinese Acad Sci, Inst Chem, CAS Key Lab Engn Plast, Joint Lab Polymer Sci & Mat, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100080, Peoples R China 3.Penn State Univ, Dept Mat Sci & Engn, University Pk, PA 16802 USA
推荐引用方式 GB/T 7714	Zou, JF,Cao, CG,Dong, JY,et al. Synthesis and functionalization of isotactic poly(propylene) containing pendant styrene groups[J]. MACROMOLECULAR RAPID COMMUNICATIONS,2004,25(20):1797-1804.
APA	Zou, JF,Cao, CG,Dong, JY,Hu, YL,&Chung, TC.(2004).Synthesis and functionalization of isotactic poly(propylene) containing pendant styrene groups.MACROMOLECULAR RAPID COMMUNICATIONS,25(20),1797-1804.
MLA	Zou, JF,et al."Synthesis and functionalization of isotactic poly(propylene) containing pendant styrene groups".MACROMOLECULAR RAPID COMMUNICATIONS 25.20(2004):1797-1804.