Aerobic oxidation of cyclohexanol to cyclohexanone in compressed CO2 and liquid solvents

doi:10.1021/ie030040m

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	Aerobic oxidation of cyclohexanol to cyclohexanone in compressed CO2 and liquid solvents
	Chang, YH; Jiang, T; Han, BX; Gao, LA; Zhang, R; Liu, ZM; Wu, WZ
刊名	INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
	2003-12-10
卷号	42 期号:25 页码:6384-6388
ISSN号	0888-5885
DOI	10.1021/ie030040m
英文摘要	The aerobic oxidation of cyclohexanol to cyclohexanone was conducted in compressed CO2 With a copper-based catalyst, and the effect of phase behavior and a small amount of cosolvents (toluene or fluorobenzene) on the conversion and selectivity of the reaction in supercritical (SC) CO2 was studied. To explore the advantages of the reaction in compressed CO2, the reaction was also performed in liquid toluene and fluorobenzene and in the absence of solvent for comparison. The results indicated that the selectivity of the reaction in compressed CO2 with and without cosolvents was much higher than that in the liquid solvents or without solvent. The conversion of cyclohexanol was improved effectively by adding a small amount of the cosolvents and the selectivity for the desired product was still very high. It was advantageous to carry out the reaction in CO2.
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000187119200016
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/80405]
专题	中国科学院化学研究所
通讯作者	Han, BX
作者单位	Chinese Acad Sci, Ctr Mol Sci, Beijing 100080, Peoples R China
推荐引用方式 GB/T 7714	Chang, YH,Jiang, T,Han, BX,et al. Aerobic oxidation of cyclohexanol to cyclohexanone in compressed CO2 and liquid solvents[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2003,42(25):6384-6388.
APA	Chang, YH.,Jiang, T.,Han, BX.,Gao, LA.,Zhang, R.,...&Wu, WZ.(2003).Aerobic oxidation of cyclohexanol to cyclohexanone in compressed CO2 and liquid solvents.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,42(25),6384-6388.
MLA	Chang, YH,et al."Aerobic oxidation of cyclohexanol to cyclohexanone in compressed CO2 and liquid solvents".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 42.25(2003):6384-6388.