Synthesis of dendritic BINAP ligands and their applications in asymmetric hydrogenation

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	Synthesis of dendritic BINAP ligands and their applications in asymmetric hydrogenation
	Deng, GJ ; Fan, QH ; Chen, XM
刊名	CHINESE JOURNAL OF CHEMISTRY
	2002-11-01
卷号	20 期号:11 页码:1139-1141
关键词	Asymmetric Hydrogenation Dendritic Catalyst Binap Homogeneous Catalysis
ISSN号	1001-604X
英文摘要	A new type of chiral dendritic ligands with 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl (BINAP) located at the focal point of the dendrimer has been synthesized through the condensation reaction of 5 ammo BINAP mid Frechet-type poly (aryl ether) dendrons with carboxyl groups as the linker high reaction yields, respectively. The ruthenium. complexes of these dendritic ligands were found to be very efficient catalysts in asymmetric hydrogenation of 2-phenylacryclic adds as well as facile catalyst recycling.
语种	英语
出版者	SCIENCE CHINA PRESS
WOS记录号	WOS:000179210800002
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/79339]
专题	中国科学院化学研究所
通讯作者	Fan, QH
作者单位	1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China 2.Nankai Univ, State Key Lab Elemento Organ Chem, Tianjin 300071, Peoples R China
推荐引用方式 GB/T 7714	Deng, GJ,Fan, QH,Chen, XM. Synthesis of dendritic BINAP ligands and their applications in asymmetric hydrogenation[J]. CHINESE JOURNAL OF CHEMISTRY,2002,20(11):1139-1141.
APA	Deng, GJ,Fan, QH,&Chen, XM.(2002).Synthesis of dendritic BINAP ligands and their applications in asymmetric hydrogenation.CHINESE JOURNAL OF CHEMISTRY,20(11),1139-1141.
MLA	Deng, GJ,et al."Synthesis of dendritic BINAP ligands and their applications in asymmetric hydrogenation".CHINESE JOURNAL OF CHEMISTRY 20.11(2002):1139-1141.