Two-phase hydroformylation reaction catalysed by rhodium-complexed water-soluble dendrimers

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	Two-phase hydroformylation reaction catalysed by rhodium-complexed water-soluble dendrimers
	Gong, AJ; Fan, QH; Chen, YM; Liu, HW; Chen, CF; Xi, F
刊名	JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
	2000-10-02
卷号	159 期号:2 页码:225-232
关键词	Dendrimer Water-soluble Ligand Two-phase Hydroformylation
ISSN号	1381-1169
英文摘要	Four water-soluble dendritic phosphonated Ligands were first synthesized based on poly(amidoamine) (PAMAM) (generation 3 with 32 cascade end groups), with the hydrophilic amine or sulfonic acid groups on the surface of the dendrimer. Their Rh(I) complexes were used as the catalysts in the two-phase hydroformylation of styrene and 1-octene at mild reaction conditions. The results showed that these new water-soluble dendritic catalysts exhibited high catalytic activity both for 1-octene and styrene. These new catalysts also exhibited high selectivity for the iso-aromatic aldehyde, while in the long chain olefin case the selectivity was benefited for normal aldehyde. (C) 2000 Elsevier Science B.V. All rights reserved.
语种	英语
出版者	ELSEVIER SCIENCE BV
WOS记录号	WOS:000089431200008
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/76429]
专题	中国科学院化学研究所
通讯作者	Xi, F
作者单位	Chinese Acad Sci, Inst Chem, Ctr Mol Sci, PCLCC, Beijing 100080, Peoples R China
推荐引用方式 GB/T 7714	Gong, AJ,Fan, QH,Chen, YM,et al. Two-phase hydroformylation reaction catalysed by rhodium-complexed water-soluble dendrimers[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,2000,159(2):225-232.
APA	Gong, AJ,Fan, QH,Chen, YM,Liu, HW,Chen, CF,&Xi, F.(2000).Two-phase hydroformylation reaction catalysed by rhodium-complexed water-soluble dendrimers.JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,159(2),225-232.
MLA	Gong, AJ,et al."Two-phase hydroformylation reaction catalysed by rhodium-complexed water-soluble dendrimers".JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 159.2(2000):225-232.