THE APPLICATION OF STRUCTURAL DATA TO THE RESEARCH ON CHEMICAL REACTION PATHWAYS, I. DYNAMIC STEREOCHEMISTRY OF FIVE-COORDINATE MOLYBDENUM COMPOUNDS Mo(L)(5)

doi:10.3866/PKU.WHXB19870501

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	THE APPLICATION OF STRUCTURAL DATA TO THE RESEARCH ON CHEMICAL REACTION PATHWAYS, I. DYNAMIC STEREOCHEMISTRY OF FIVE-COORDINATE MOLYBDENUM COMPOUNDS Mo(L)(5)
	Liao Daiqing; Fu Heng; Tang Yougi
刊名	ACTA PHYSICO-CHIMICA SINICA
	1987
卷号	3 期号:5 页码:449-452
ISSN号	1000-6818
DOI	10.3866/PKU.WHXB19870501
英文摘要	The principle of structure correlation is applied to 28 crystal structures which contain 44 different five coordinate molybdenum fragments. The tints derived map the reaction pathway for a bimolecular ligand substitution reaction at tetrahedral molybdenum centers. The dihedral angle method from Muetteries and Guggenberger is employed in order to describe the interconversion between the trigonal bipyramidal (TBP) and tit square pramidal (SQP) conformations via the Berry pseudorotation mechanism in the system of Mo (L)(5) complexes. The structure correlation method provides a convincing mapping of the Berry pathway in this paper.
语种	英语
出版者	PEKING UNIV PRESS
WOS记录号	WOS:000207569500001
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/73989]
专题	中国科学院化学研究所
通讯作者	Liao Daiqing
作者单位	Acad Sinica, Inst Chem, Beijing 100080, Peoples R China
推荐引用方式 GB/T 7714	Liao Daiqing,Fu Heng,Tang Yougi. THE APPLICATION OF STRUCTURAL DATA TO THE RESEARCH ON CHEMICAL REACTION PATHWAYS, I. DYNAMIC STEREOCHEMISTRY OF FIVE-COORDINATE MOLYBDENUM COMPOUNDS Mo(L)(5)[J]. ACTA PHYSICO-CHIMICA SINICA,1987,3(5):449-452.
APA	Liao Daiqing,Fu Heng,&Tang Yougi.(1987).THE APPLICATION OF STRUCTURAL DATA TO THE RESEARCH ON CHEMICAL REACTION PATHWAYS, I. DYNAMIC STEREOCHEMISTRY OF FIVE-COORDINATE MOLYBDENUM COMPOUNDS Mo(L)(5).ACTA PHYSICO-CHIMICA SINICA,3(5),449-452.
MLA	Liao Daiqing,et al."THE APPLICATION OF STRUCTURAL DATA TO THE RESEARCH ON CHEMICAL REACTION PATHWAYS, I. DYNAMIC STEREOCHEMISTRY OF FIVE-COORDINATE MOLYBDENUM COMPOUNDS Mo(L)(5)".ACTA PHYSICO-CHIMICA SINICA 3.5(1987):449-452.