Iron(III)-Promoted Oxidative Coupling of Naphthylamines: Synthetic and Mechanistic Investigations

doi:10.1021/ol202058r

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	Iron(III)-Promoted Oxidative Coupling of Naphthylamines: Synthetic and Mechanistic Investigations
	Li, Xin-Le 1,2; Huang, Jin-Hua 1,2; Yang, Lian-Ming 1
刊名	ORGANIC LETTERS
	2011-09-16
卷号	13 期号:18 页码:4950-4953
ISSN号	1523-7060
DOI	10.1021/ol202058r
英文摘要	A facile route to the synthesis of 1,1'-binaphthyl-4,4'-diamines (naphthidines) and 1,1'-binaphthyl-2,2'-diamines (BINAMs) was developed by the oxidative homocoupling of 1- and 2-naphthylamines, respectively, using FeCl(3) as oxidant and K(2)CO(3) as base in 1,2-dichloroethane under ambient conditions. A preliminary mechanistic investigation was performed by the ESR spectroscopy and intermediate-trapping technique.
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000294703900051
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/72291]
专题	中国科学院化学研究所
通讯作者	Yang, Lian-Ming
作者单位	1.Chinese Acad Sci, BNLMS, New Mat Lab, Inst Chem, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Li, Xin-Le,Huang, Jin-Hua,Yang, Lian-Ming. Iron(III)-Promoted Oxidative Coupling of Naphthylamines: Synthetic and Mechanistic Investigations[J]. ORGANIC LETTERS,2011,13(18):4950-4953.
APA	Li, Xin-Le,Huang, Jin-Hua,&Yang, Lian-Ming.(2011).Iron(III)-Promoted Oxidative Coupling of Naphthylamines: Synthetic and Mechanistic Investigations.ORGANIC LETTERS,13(18),4950-4953.
MLA	Li, Xin-Le,et al."Iron(III)-Promoted Oxidative Coupling of Naphthylamines: Synthetic and Mechanistic Investigations".ORGANIC LETTERS 13.18(2011):4950-4953.