One-Pot Synthesis and Unpredicted Hydrogen Bonds of the Guanidinium Triflates from Readily Available Amines, Carbodiimides, and Zn(OTf)(2)

doi:10.1021/om2006613

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	One-Pot Synthesis and Unpredicted Hydrogen Bonds of the Guanidinium Triflates from Readily Available Amines, Carbodiimides, and Zn(OTf)(2)
	Li, Dongzhen 1; Wang, Yang 1; Zhang, Wen-Xiong 1,2; Zhang, Shaoguang 1; Guang, Jie 1; Xi, Zhenfeng 1
刊名	ORGANOMETALLICS
	2011-10-10
卷号	30 期号:19 页码:5278-5283
ISSN号	0276-7333
DOI	10.1021/om2006613
英文摘要	The first synthesis of trisubstituted guanidinium triflates has been achieved by a simple one-step procedure from readily available amines, carbodiimides, and Zn(OTf)(2). X-ray analysis revealed they adopt 1-D chain-like or novel 3-D hydrogen-bonded networks, which have not been reported previously in the solid structure of guanidinium salts. Isolation of a binuclear zinc complex and its subsequent carbodiimide insertion provide the insight into the mechanism for the formation of guanidinium triflates.
语种	英语
出版者	AMER CHEMICAL SOC
WOS记录号	WOS:000295347600025
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/72209]
专题	中国科学院化学研究所
通讯作者	Zhang, Wen-Xiong
作者单位	1.Peking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem, Beijing 100871, Peoples R China 2.Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China
推荐引用方式 GB/T 7714	Li, Dongzhen,Wang, Yang,Zhang, Wen-Xiong,et al. One-Pot Synthesis and Unpredicted Hydrogen Bonds of the Guanidinium Triflates from Readily Available Amines, Carbodiimides, and Zn(OTf)(2)[J]. ORGANOMETALLICS,2011,30(19):5278-5283.
APA	Li, Dongzhen,Wang, Yang,Zhang, Wen-Xiong,Zhang, Shaoguang,Guang, Jie,&Xi, Zhenfeng.(2011).One-Pot Synthesis and Unpredicted Hydrogen Bonds of the Guanidinium Triflates from Readily Available Amines, Carbodiimides, and Zn(OTf)(2).ORGANOMETALLICS,30(19),5278-5283.
MLA	Li, Dongzhen,et al."One-Pot Synthesis and Unpredicted Hydrogen Bonds of the Guanidinium Triflates from Readily Available Amines, Carbodiimides, and Zn(OTf)(2)".ORGANOMETALLICS 30.19(2011):5278-5283.