Rational Design of Low-Temperature Hydrogenation Catalysts: Theoretical Predictions and Experimental Verification

doi:10.3866/PKU.WHXB20100441

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	Rational Design of Low-Temperature Hydrogenation Catalysts: Theoretical Predictions and Experimental Verification
	Chen, Jingguang G.1; Qi Sui-Tao 1,2; Humbert, Michael P.1; Menning, Carl A.1; Zhu Yue-Xiang 3
刊名	ACTA PHYSICO-CHIMICA SINICA
	2010-04-01
卷号	26 期号:4 页码:869-876
关键词	Hydrogenation Bimetallic Catalyst Metal Carbide Density Functional Calculation
ISSN号	1000-6818
DOI	10.3866/PKU.WHXB20100441
英文摘要	In this review, we will provide a brief review of our recent theoretical and experimental studies of bimetallic surfaces and catalysts for the low-temperature hydrogenation of unsaturated C=C and C=O bonds. We will first use the hydrogenation of cyclohexene as a probe reaction to demonstrate the importance of using several parallel approaches. including fundamental surface science and density functional theory (DFT) studies on single crystal surfaces, synthesis. and characterization of polycrystalline surfaces and supported catalysts, and reactor evaluation of supported catalysts. We will then provide a summary of applications of bimetallic catalysts for other hydrogenation reactions, including the selective hydrogenation of the C=O bond in acrolein. the low-temperature hydrogenation of benzene. and the selective hydrogenation of acetylene in the presence of ethylene Finally, we will discuss the possibility of replacing the platinum (Pt) component with metal carbides to reduce the loading of Pt in bimetallic catalysts
语种	英语
出版者	PEKING UNIV PRESS
WOS记录号	WOS:000276958400012
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/69409]
专题	中国科学院化学研究所
通讯作者	Chen, Jingguang G.
作者单位	1.Univ Delaware, Ctr Catalyt Sci & Technol, Dept Chem Engn, Newark, DE 19716 USA 2.Xi An Jiao Tong Univ, Dept Chem Engn, Xian 710049, Peoples R China 3.Peking Univ, Coll Chem & Mol Engn, State Key Lab Struct Chem Unstable & Stable Speci, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China
推荐引用方式 GB/T 7714	Chen, Jingguang G.,Qi Sui-Tao,Humbert, Michael P.,et al. Rational Design of Low-Temperature Hydrogenation Catalysts: Theoretical Predictions and Experimental Verification[J]. ACTA PHYSICO-CHIMICA SINICA,2010,26(4):869-876.
APA	Chen, Jingguang G.,Qi Sui-Tao,Humbert, Michael P.,Menning, Carl A.,&Zhu Yue-Xiang.(2010).Rational Design of Low-Temperature Hydrogenation Catalysts: Theoretical Predictions and Experimental Verification.ACTA PHYSICO-CHIMICA SINICA,26(4),869-876.
MLA	Chen, Jingguang G.,et al."Rational Design of Low-Temperature Hydrogenation Catalysts: Theoretical Predictions and Experimental Verification".ACTA PHYSICO-CHIMICA SINICA 26.4(2010):869-876.