Kumada chain-growth polycondensation as a universal method for synthesis of well-defined conjugated polymers

doi:10.1007/s11426-010-4048-2

CORC > 化学研究所 > 中国科学院化学研究所

	Kumada chain-growth polycondensation as a universal method for synthesis of well-defined conjugated polymers
	Geng YanHou 1,2; Huang Li 1,2,3; Wu ShuPeng 1,2,3; Wang FoSong 1,2
刊名	SCIENCE CHINA-CHEMISTRY
	2010-08-01
卷号	53 期号:8 页码:1620-1633
关键词	Chain Growth Polycondensation Conjugated Polymers Kumada Reaction Block Copolymers Polymer Brush
ISSN号	1674-7291
DOI	10.1007/s11426-010-4048-2
英文摘要	Kumada chain-growth polycondensation (KCGP) is a novel method for the synthesis of well-defined conjugated polymers. Because the Ni-catalyst can transfer in an intramolecular process to the propagating chain end, the polymerization follows chain-growth mechanism. With this newly developed method, various conjugated polymers, such as polythiophenes, poly(p-phenylene) (PPP), polypyrrole (PPy), and polyfluorene with controlled molecular weights and relatively narrow polydispersities (PDIs), have been prepared. Especially, the polymerizations for poly(3-alkylthiophene)s (P3ATs), PPP, and PPy exhibited quasi-living characteristics, which allows preparing polymer brushes, fully-conjugated block copolymers, and macroinitiators and macro-reactants for the synthesis of rod-coil block copolymers. In the current review, the progress in this new area is summarized.
语种	英语
出版者	SCIENCE PRESS
WOS记录号	WOS:000281403400003
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/68849]
专题	中国科学院化学研究所
通讯作者	Geng YanHou
作者单位	1.Chinese Acad Sci, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Changchun Inst Appl Chem, Changchun 130022, Peoples R China 3.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Geng YanHou,Huang Li,Wu ShuPeng,et al. Kumada chain-growth polycondensation as a universal method for synthesis of well-defined conjugated polymers[J]. SCIENCE CHINA-CHEMISTRY,2010,53(8):1620-1633.
APA	Geng YanHou,Huang Li,Wu ShuPeng,&Wang FoSong.(2010).Kumada chain-growth polycondensation as a universal method for synthesis of well-defined conjugated polymers.SCIENCE CHINA-CHEMISTRY,53(8),1620-1633.
MLA	Geng YanHou,et al."Kumada chain-growth polycondensation as a universal method for synthesis of well-defined conjugated polymers".SCIENCE CHINA-CHEMISTRY 53.8(2010):1620-1633.