Zn(OTf)(2)-catalyzed addition of amines to carbodiimides: efficient synthesis of guanidines and unpredicted formation of Zn-N amido species

doi:10.1039/b923249b

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	Zn(OTf)(2)-catalyzed addition of amines to carbodiimides: efficient synthesis of guanidines and unpredicted formation of Zn-N amido species
	Li, Dongzhen 1,2; Guang, Jie 1,2; Zhang, Wen-Xiong 1,2,3; Wang, Yang 1,2; Xi, Zhenfeng 1,2
刊名	ORGANIC & BIOMOLECULAR CHEMISTRY
	2010
卷号	8 期号:8 页码:1816-1820
ISSN号	1477-0520
DOI	10.1039/b923249b
英文摘要	Zn(OTf)(2) acts as an excellent catalyst precursor for addition of various amine N-H bonds to carbodiimides under an atmosphere of air, offering a convenient synthesis of substituted guanidines with high functional-group tolerance. A Zn-N amido species is shown to act as the active species.
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000276192100011
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/68765]
专题	中国科学院化学研究所
通讯作者	Zhang, Wen-Xiong
作者单位	1.Peking Univ, Coll Chem, BNLMS, Beijing 100871, Peoples R China 2.Peking Univ, Coll Chem, Minist Educ, Key Lab Bioorgan Chem & Mol Engn, Beijing 100871, Peoples R China 3.Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China
推荐引用方式 GB/T 7714	Li, Dongzhen,Guang, Jie,Zhang, Wen-Xiong,et al. Zn(OTf)(2)-catalyzed addition of amines to carbodiimides: efficient synthesis of guanidines and unpredicted formation of Zn-N amido species[J]. ORGANIC & BIOMOLECULAR CHEMISTRY,2010,8(8):1816-1820.
APA	Li, Dongzhen,Guang, Jie,Zhang, Wen-Xiong,Wang, Yang,&Xi, Zhenfeng.(2010).Zn(OTf)(2)-catalyzed addition of amines to carbodiimides: efficient synthesis of guanidines and unpredicted formation of Zn-N amido species.ORGANIC & BIOMOLECULAR CHEMISTRY,8(8),1816-1820.
MLA	Li, Dongzhen,et al."Zn(OTf)(2)-catalyzed addition of amines to carbodiimides: efficient synthesis of guanidines and unpredicted formation of Zn-N amido species".ORGANIC & BIOMOLECULAR CHEMISTRY 8.8(2010):1816-1820.