SYNTHESIS AND CHARACTERIZATION OF CONDUCTIVE POLY(m-TOLUIDINE) HOLLOW MICROSPHERES

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	SYNTHESIS AND CHARACTERIZATION OF CONDUCTIVE POLY(m-TOLUIDINE) HOLLOW MICROSPHERES
	He Haiyong 1,2; Zhu Ying 1; Li Xin 1; Wang Qibao 2; Wan Meixiang 1; Jiang Lei 1
刊名	ACTA POLYMERICA SINICA
	2008-12-20
期号	12 页码:1181-1184
关键词	Poly(M-toluidine) Ammonium Persulfate Hollow Microspheres Template-free Method Self-assembly
ISSN号	1000-3304
英文摘要	Self-assembled hollow microspheres of conductive poly( m-toluidine) (PMT) were simply synthesized by a template-free method in the presence of ammonium peroxydisulfate (APS) without adding an acidic dopant. The average diameter and the average shell thickness of the PMT hollow microspheres were measured to be 2 mu m and 140 nm, respectively. Although without adding acids as the dopants, it has been demonstrated that the PMT hollow microspheres are identical to the conducting state of PMT due to proton (H(2)SO(4)) produced during the polymerization, which are conformed by FTIR, UV-Visible spectroscopy and room-temperature conductivity measured by the four-probe method, especially the pH value in reaction solution decreases with increasing the polymerization time. It was proposed that a spherical micelles composed of m-toluidine in aqueous solutions is served as a soft-template in forming the PMT hollow spheres via a self-assembly process.
语种	英语
出版者	SCIENCE PRESS
WOS记录号	WOS:000262112700010
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/64135]
专题	中国科学院化学研究所
通讯作者	He Haiyong
作者单位	1.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China 2.China Univ Min & Technol, Sch Chem & Environm Engn, Beijing 100083, Peoples R China
推荐引用方式 GB/T 7714	He Haiyong,Zhu Ying,Li Xin,et al. SYNTHESIS AND CHARACTERIZATION OF CONDUCTIVE POLY(m-TOLUIDINE) HOLLOW MICROSPHERES[J]. ACTA POLYMERICA SINICA,2008(12):1181-1184.
APA	He Haiyong,Zhu Ying,Li Xin,Wang Qibao,Wan Meixiang,&Jiang Lei.(2008).SYNTHESIS AND CHARACTERIZATION OF CONDUCTIVE POLY(m-TOLUIDINE) HOLLOW MICROSPHERES.ACTA POLYMERICA SINICA(12),1181-1184.
MLA	He Haiyong,et al."SYNTHESIS AND CHARACTERIZATION OF CONDUCTIVE POLY(m-TOLUIDINE) HOLLOW MICROSPHERES".ACTA POLYMERICA SINICA .12(2008):1181-1184.