Promoting effect of transition metal salts on rhodium catalyzed methanol carbonylation | |
Zhang, Shufeng; Qian, Qingli; Yuan, Guoqing | |
刊名 | CATALYSIS COMMUNICATIONS |
2006-11-01 | |
卷号 | 7期号:11页码:885-888 |
关键词 | Methanol Carbonylation Rhodium Catalyst Transition Metal Salts Catalytic Activity |
ISSN号 | 1566-7367 |
DOI | 10.1016/j.catcom.2006.03.017 |
英文摘要 | Some transition metal chlorides were used as promoters for homogeneous rhodium catalyzed methanol carbonylation. The experiments were carried out at low water conditions. All of the catalysts with the promoters demonstrate better catalytic activity than the pristine Monsanto catalyst. Ni, Fe and Co chlorides are most efficient promoters, among which Ni manifest the best performance in accelerating the catalytic rate. All the experiments promoted by such promoters demonstrate good stability and catalytic selectivity. (c) 2006 Elsevier B.V. All rights reserved. |
语种 | 英语 |
出版者 | ELSEVIER SCIENCE BV |
WOS记录号 | WOS:000242037200011 |
内容类型 | 期刊论文 |
源URL | [http://ir.iccas.ac.cn/handle/121111/59591] |
专题 | 中国科学院化学研究所 |
通讯作者 | Yuan, Guoqing |
作者单位 | 1.Tianjin Normal Univ, Coll Chem & Life Sci, Tianjin 300074, Peoples R China 2.Chinese Acad Sci, Inst Chem, Lab New Mat, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, Shufeng,Qian, Qingli,Yuan, Guoqing. Promoting effect of transition metal salts on rhodium catalyzed methanol carbonylation[J]. CATALYSIS COMMUNICATIONS,2006,7(11):885-888. |
APA | Zhang, Shufeng,Qian, Qingli,&Yuan, Guoqing.(2006).Promoting effect of transition metal salts on rhodium catalyzed methanol carbonylation.CATALYSIS COMMUNICATIONS,7(11),885-888. |
MLA | Zhang, Shufeng,et al."Promoting effect of transition metal salts on rhodium catalyzed methanol carbonylation".CATALYSIS COMMUNICATIONS 7.11(2006):885-888. |
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