Surface structure of heterogeneous catalysts: Cinchona and tartaric acid on solid surface

doi:10.1007/s11244-005-3818-0

CORC > 化学研究所 > 中国科学院化学研究所

	Surface structure of heterogeneous catalysts: Cinchona and tartaric acid on solid surface
	Wang, D; Yan, HJ; Xu, QM; Han, MJ; Wan, LJ
刊名	TOPICS IN CATALYSIS
	2005-06-01
卷号	35 期号:1-2 页码:131-139
ISSN号	1022-5528
DOI	10.1007/s11244-005-3818-0
英文摘要	Enantioselective hydrogenation by heterogeneous catalysts has gained great importance in organic synthesis, chemical engineering and pharmaceutical industry. However, the mechanism of enantioselectivity is not well understood due to the absence of evidence at the molecular level. Recently, the great advance on this topic has been made by applying scanning tunneling microscopy (STM) and other surface characterization techniques to get direct evidence about the enantioselective mechanism of catalysts. Here, the progress on the adsorption mode of chiral modifiers such as cinchona and tartaric acid and the related enantioselective mechanism is reviewed from the viewpoint of surface science. Particularly, some STM works on this topic are summarized. Finally, several key issues for further investigation are outlined.
语种	英语
出版者	SPRINGER/PLENUM PUBLISHERS
WOS记录号	WOS:000231311300012
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/56585]
专题	中国科学院化学研究所
通讯作者	Wan, LJ
作者单位	Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
推荐引用方式 GB/T 7714	Wang, D,Yan, HJ,Xu, QM,et al. Surface structure of heterogeneous catalysts: Cinchona and tartaric acid on solid surface[J]. TOPICS IN CATALYSIS,2005,35(1-2):131-139.
APA	Wang, D,Yan, HJ,Xu, QM,Han, MJ,&Wan, LJ.(2005).Surface structure of heterogeneous catalysts: Cinchona and tartaric acid on solid surface.TOPICS IN CATALYSIS,35(1-2),131-139.
MLA	Wang, D,et al."Surface structure of heterogeneous catalysts: Cinchona and tartaric acid on solid surface".TOPICS IN CATALYSIS 35.1-2(2005):131-139.