Solubilities of Methane in Mixed Solvents of Water and t-butye Alcohol

doi:10.3866/PKU.WHXB19940605

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	Solubilities of Methane in Mixed Solvents of Water and t-butye Alcohol
	Pan Jingjun 1; Han Buxing 1; Yan Haike 1; Li Zhifen 2; Liu Ruilin 2
刊名	ACTA PHYSICO-CHIMICA SINICA
	1994
卷号	10 期号:6 页码:501-507
关键词	Methane Water T-butyl Alcohol Gas Solubility Thermodynamic Properties
ISSN号	1000-6818
DOI	10.3866/PKU.WHXB19940605
英文摘要	Solubilities of met. e in binary mixtures of water and t-butyl alcohol (TBA) have been measured in the temperature range from 303.15 K to 333.15 K and at pressures up to 6MPa.The mole fraction of t-butyl alcohol(z(TBA)) in the mixed solvents varied from 0.0 to 1.0. The dependence of the solubilities on temperature and the composition of the mixed solvents can be explained by clathrate structure in the mixed solvents. The Henry's Law constants, the partial mole volumes of methane in the solvents, and the standard thermodynamic functions (Delta G degrees, Delta H degrees, Delta S degrees)have been calculated and discussed.
语种	英语
出版者	PEKING UNIV PRESS
WOS记录号	WOS:000207589300005
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/55009]
专题	中国科学院化学研究所
通讯作者	Pan Jingjun
作者单位	1.Acad Sinica, Inst Chem, Beijing 100080, Peoples R China 2.Peking Univ, Inst Phys Chem, Beijing 100087, Peoples R China
推荐引用方式 GB/T 7714	Pan Jingjun,Han Buxing,Yan Haike,et al. Solubilities of Methane in Mixed Solvents of Water and t-butye Alcohol[J]. ACTA PHYSICO-CHIMICA SINICA,1994,10(6):501-507.
APA	Pan Jingjun,Han Buxing,Yan Haike,Li Zhifen,&Liu Ruilin.(1994).Solubilities of Methane in Mixed Solvents of Water and t-butye Alcohol.ACTA PHYSICO-CHIMICA SINICA,10(6),501-507.
MLA	Pan Jingjun,et al."Solubilities of Methane in Mixed Solvents of Water and t-butye Alcohol".ACTA PHYSICO-CHIMICA SINICA 10.6(1994):501-507.