Fluoro-functionalized polymeric ionic liquids: highly efficient catalysts for CO2 cycloaddition to cyclic carbonates under mild conditions

doi:10.1039/c4gc00730a

CORC > 化学研究所 > 中国科学院化学研究所

	Fluoro-functionalized polymeric ionic liquids: highly efficient catalysts for CO2 cycloaddition to cyclic carbonates under mild conditions
	Yang, Zhen-Zhen; Zhao, Yanfei; Ji, Guipeng; Zhang, Hongye; Yu, Bo; Gao, Xiang; Liu, Zhimin
刊名	GREEN CHEMISTRY
	2014-08-01
卷号	16 期号:8 页码:3724-3728
ISSN号	1463-9262
DOI	10.1039/c4gc00730a
英文摘要	Fluoro-functionalized polymeric ionic liquids (F-PILs) with imidazolium cations and bromide or chloride anions were designed for cycloaddition reactions of CO2 with epoxides. It was found that the fluorine content in F-PILs significantly influenced the catalytic activity of the catalysts, and F-PIL-Br showed three times higher activity for CO2 reacting with styrene oxide than non-fluorous PIL-Br. Moreover, F-PIL-Br could be extended to catalyse a broad range of reactants under 1 MPa CO2 pressure, producing a series of cyclic carbonates in excellent yields (93-99%). In addition, it showed high stability and easy recyclability.
语种	英语
出版者	ROYAL SOC CHEMISTRY
WOS记录号	WOS:000340017000007
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/52221]
专题	中国科学院化学研究所
通讯作者	Yang, Zhen-Zhen
作者单位	Chinese Acad Sci, Inst Chem, Key Lab Colloid Interface & Thermodynam, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Yang, Zhen-Zhen,Zhao, Yanfei,Ji, Guipeng,et al. Fluoro-functionalized polymeric ionic liquids: highly efficient catalysts for CO2 cycloaddition to cyclic carbonates under mild conditions[J]. GREEN CHEMISTRY,2014,16(8):3724-3728.
APA	Yang, Zhen-Zhen.,Zhao, Yanfei.,Ji, Guipeng.,Zhang, Hongye.,Yu, Bo.,...&Liu, Zhimin.(2014).Fluoro-functionalized polymeric ionic liquids: highly efficient catalysts for CO2 cycloaddition to cyclic carbonates under mild conditions.GREEN CHEMISTRY,16(8),3724-3728.
MLA	Yang, Zhen-Zhen,et al."Fluoro-functionalized polymeric ionic liquids: highly efficient catalysts for CO2 cycloaddition to cyclic carbonates under mild conditions".GREEN CHEMISTRY 16.8(2014):3724-3728.