Synthesis and Structure of Azacalix[2]pyrimidine[2]triazines and Their Self-assembly in the Solid State

doi:10.1002/cjoc.201400505

CORC > 化学研究所 > 中国科学院化学研究所

	Synthesis and Structure of Azacalix[2]pyrimidine[2]triazines and Their Self-assembly in the Solid State
	Wang, Lixia 1; Wang, Dexian 1; Wang, Meixiang 2
刊名	CHINESE JOURNAL OF CHEMISTRY
	2014-10-01
卷号	32 期号:10 页码:1033-1038
关键词	Azacalix[2]Pyrimidine[2]Triazine Fragment Coupling Approach One-pot Reaction Self-assembly Hydrogen Bond
ISSN号	1001-604X
DOI	10.1002/cjoc.201400505
英文摘要	A number of azacalix[2]pyrimidine[2]triazines were synthesized in moderate to good yields from both a step-wise fragment coupling approach and a one-pot reaction strategy starting from 4,6-diaminopyrimidines and cyanuric chloride. Nucleophilic aromatic substitution reaction of resulting dichloro-substituted azacalix[2]pyrimidine[2]triazines with NH4Cl led to the formation of NH2-bearing azacalix[2]pyrimidine[2]triazine analogs. Azacalix[2]pyrimidine[2]triazines adopted symmetric 1,3-alternate conformations in solution while twisted 1,3-alternate conformations were observed in the solid state. In the presence of different additives during the growth of single crystals, azacalix[2]pyrimidine[2]triazines containing amino (-NH2) groups gave varied self-assembled structures due to the formation of different intermolecular hydrogen bond motifs.
语种	英语
出版者	WILEY-V C H VERLAG GMBH
WOS记录号	WOS:000343871100017
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/52209]
专题	中国科学院化学研究所
通讯作者	Wang, Dexian
作者单位	1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Key Lab Mol Recognit & Funct, Inst Chem, Beijing 100190, Peoples R China 2.Tsinghua Univ, Dept Chem, Key Lab Bioorgan Phosphorus Chem & Chem Biol, Beijing 100084, Peoples R China
推荐引用方式 GB/T 7714	Wang, Lixia,Wang, Dexian,Wang, Meixiang. Synthesis and Structure of Azacalix[2]pyrimidine[2]triazines and Their Self-assembly in the Solid State[J]. CHINESE JOURNAL OF CHEMISTRY,2014,32(10):1033-1038.
APA	Wang, Lixia,Wang, Dexian,&Wang, Meixiang.(2014).Synthesis and Structure of Azacalix[2]pyrimidine[2]triazines and Their Self-assembly in the Solid State.CHINESE JOURNAL OF CHEMISTRY,32(10),1033-1038.
MLA	Wang, Lixia,et al."Synthesis and Structure of Azacalix[2]pyrimidine[2]triazines and Their Self-assembly in the Solid State".CHINESE JOURNAL OF CHEMISTRY 32.10(2014):1033-1038.